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dc.contributor.authorGuan, Chao
dc.contributor.authorZhang, Dandan
dc.contributor.authorPan, Yupeng
dc.contributor.authorIguchi, Masayuki
dc.contributor.authorAjitha, Manjaly John
dc.contributor.authorHu, Jinsong
dc.contributor.authorLi, Huaifeng
dc.contributor.authorYao, Changguang
dc.contributor.authorHuang, Mei-Hui
dc.contributor.authorMin, Shixiong
dc.contributor.authorZheng, Junrong
dc.contributor.authorHimeda, Yuichiro
dc.contributor.authorKawanami, Hajime
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2017-01-29T13:51:39Z
dc.date.available2017-01-29T13:51:39Z
dc.date.issued2016-12-17
dc.identifier.citationGuan C, Zhang D-D, Pan Y, Iguchi M, Ajitha MJ, et al. (2017) Dehydrogenation of Formic Acid Catalyzed by a Ruthenium Complex with an N,N′-Diimine Ligand. Inorganic Chemistry 56: 438–445. Available: http://dx.doi.org/10.1021/acs.inorgchem.6b02334.
dc.identifier.issn0020-1669
dc.identifier.issn1520-510X
dc.identifier.doi10.1021/acs.inorgchem.6b02334
dc.identifier.urihttp://hdl.handle.net/10754/622782
dc.description.abstractWe report a ruthenium complex containing an N,N′-diimine ligand for the selective decomposition of formic acid to H and CO in water in the absence of any organic additives. A turnover frequency of 12000 h and a turnover number of 350 000 at 90 °C were achieved in the HCOOH/HCOONa aqueous solution. Efficient production of high-pressure H and CO (24.0 MPa (3480 psi)) was achieved through the decomposition of formic acid with no formation of CO. Mechanistic studies by NMR and DFT calculations indicate that there may be two competitive pathways for the key hydride transfer rate-determining step in the catalytic process.
dc.description.sponsorshipThis work was supported by King Abdullah University of Science and Technology (KAUST). We thank Carolyn E. Unck for assistance with the manuscript preparation.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b02334
dc.titleDehydrogenation of Formic Acid Catalyzed by a Ruthenium Complex with an N,N′-Diimine Ligand
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalInorganic Chemistry
dc.contributor.institutionNational Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino-ku, Sendai, Miyagi, 983-8551, Japan
dc.contributor.institutionCollege of Chemistry, Peking University, Beijing, 100871, China
dc.contributor.institutionNational Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba-shi, Ibaraki, 305-8565, Japan
kaust.personGuan, Chao
kaust.personZhang, Dandan
kaust.personPan, Yupeng
kaust.personAjitha, Manjaly John
kaust.personHu, Jinsong
kaust.personLi, Huaifeng
kaust.personYao, Changguang
kaust.personHuang, Mei-Hui
kaust.personMin, Shixiong
kaust.personHuang, Kuo-Wei
dc.relation.isSupplementedByGuan, C., Zhang, D.-D., Pan, Y., Iguchi, M., Ajitha, M. J., Hu, J., … Huang, K.-W. (2017). CCDC 1530235: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1ncbfs
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.cc1ncbfs
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624600


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