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    Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds

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    Type
    Article
    Authors
    Rouen, Mathieu
    Queval, Pierre
    Borre, Etienne
    Falivene, Laura cc
    Poater, Albert cc
    Berthod, Mikael
    Hugues, Francois
    Cavallo, Luigi cc
    Basle, Olivier
    Olivier-Bourbigou, Helene
    Mauduit, Marc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-10-26
    Online Publication Date
    2016-10-26
    Print Publication Date
    2016-11-04
    Permanent link to this record
    http://hdl.handle.net/10754/622462
    
    Metadata
    Show full item record
    Abstract
    The search for a low-cost process for the valorization of linear alpha-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear alpha-olefins to longer internal linear olefins with high selectivity (>99%) under neat conditions at low loadings (50 ppm) and without the need of expensive additives. This robust catalytic process allowed us to efficiently and selectively re-equilibrate the naphtha fraction (C-5-C-8) of a Fischer-Tropsch feed derived from non petroleum resources to a higher-value product range (C-9-C-14), useful as detergent and plasticizer precursors.
    Citation
    Rouen M, Queval P, Borré E, Falivene L, Poater A, et al. (2016) Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds. ACS Catalysis 6: 7970–7976. Available: http://dx.doi.org/10.1021/acscatal.6b01428.
    Sponsors
    Dedicated to the memory of Yves Chauvin. This work was supported by the European Community through the seventh framework program (CP-FP 211468-2 EUMET, grant to M.R., L.F., and E.B.). M.M. thanks the CNRS, the ENSCR, Rennes Metropole, and the Region-Bretagne for their financial support. A.P. thanks the Spanish MINECO for project CTQ2014-59832-JIN, and L.C. acknowledges funding from the King Abdullah University of Science and Technology (KAUST).
    Publisher
    American Chemical Society (ACS)
    Journal
    ACS Catalysis
    DOI
    10.1021/acscatal.6b01428
    Additional Links
    http://pubs.acs.org/doi/abs/10.1021/acscatal.6b01428
    ae974a485f413a2113503eed53cd6c53
    10.1021/acscatal.6b01428
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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