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dc.contributor.authorAjitha, Manjaly John
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2017-01-02T09:28:31Z
dc.date.available2017-01-02T09:28:31Z
dc.date.issued2016-08-17
dc.identifier.citationHuang K-W, Ajitha M (2016) Non-Classical C–H···X Hydrogen Bonding and Its Role in Asymmetric Organocatalysis. Synthesis 48: 3449–3458. Available: http://dx.doi.org/10.1055/s-0035-1562475.
dc.identifier.issn0039-7881
dc.identifier.issn1437-210X
dc.identifier.doi10.1055/s-0035-1562475
dc.identifier.urihttp://hdl.handle.net/10754/622438
dc.description.abstractNon-classical hydrogen bonds (NCHBs) have attracted significant interest in the past decade particularly because of their important role in asymmetric catalytic systems. These weak interactions (< 4 kcal/mol) offer much flexibility in the preorganization of molecular entities required to achieve high enantioselectivity. Herein, we review some recent important organocatalytic asymmetric reactions where a NCHB serves as a critical factor in determining the stereoselectivity.
dc.description.abstract1 Introduction
dc.description.abstract2 Hydrogen Bonds (HBs) and Non-Classical Hydrogen Bonds (NCHBs)
dc.description.abstract3 Early Developments in NCHBs
dc.description.abstract4 Selected Examples of NCHBs in Organic Transformations
dc.description.abstract5 Recent Examples of NCHBs in Enantioselective Reactions
dc.description.abstract6 Conclusions and Outlook
dc.description.sponsorshipThis work is supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherGeorg Thieme Verlag KG
dc.relation.urlhttps://www.thieme-connect.de/DOI/DOI?10.1055/s-0035-1562475
dc.subjectnon-classical hydrogen bond
dc.subjectenantioselectivity
dc.subjectorganocatalysis
dc.subjectmechanism
dc.subjectDFT
dc.titleNon-Classical C–H···X Hydrogen Bonding and Its Role in Asymmetric Organocatalysis
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalSynthesis
kaust.personAjitha, Manjaly John
kaust.personHuang, Kuo-Wei


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