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dc.contributor.authorLi, Baiyan
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorZhang, Yiming
dc.contributor.authorBhatt, Prashant
dc.contributor.authorHe, Hongming
dc.contributor.authorZhang, Daliang
dc.contributor.authorHan, Yu
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorPerman, Jason A.
dc.contributor.authorMa, Shengqian
dc.date.accessioned2017-01-02T09:28:29Z
dc.date.available2017-01-02T09:28:29Z
dc.date.issued2016
dc.identifier.citationLi B, Belmabkhout Y, Zhang Y, Bhatt PM, He H, et al. (2016) From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation. Chem Commun 52: 13897–13900. Available: http://dx.doi.org/10.1039/C6CC08008A.
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.doi10.1039/C6CC08008A
dc.identifier.urihttp://hdl.handle.net/10754/622407
dc.description.abstractWe unveil a unique kinetic driven separation material for selectively removing linear paraffins from iso-paraffins via a molecular sieving mechanism. Subsequent carbonization and thermal treatment of CD-MOF-2, the cyclodextrin metal-organic framework, afforded a carbon molecular sieve with a uniform and reduced pore size of ca. 5.0 Å, and it exhibited highly selective kinetic separation of n-butane and n-pentane from iso-butane and iso-pentane, respectively. © The Royal Society of Chemistry.
dc.description.sponsorshipThe authors acknowledge the University of South Florida for financial support of this work. Y. B., P. M. B. and M. E. acknowledge the financial support of AMPM center collaborative funding CCF/1/1972-02-01 and CCF/1/1972-8-01. The authors thank Dr Zheng Niu, Kia Williams, and Dr Hui Yang for collecting the SEM images of CD-MOF-2.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC08008A
dc.titleFrom an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentElectron Microscopy
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentNanostructured Functional Materials (NFM) laboratory
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem. Commun.
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL, United States
kaust.personBelmabkhout, Youssef
kaust.personBhatt, Prashant
kaust.personZhang, Daliang
kaust.personHan, Yu
kaust.personEddaoudi, Mohamed


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