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    Synthesis and Characterization of the Ternary Thiobismuthates A9Bi13S24 (A = K, Rb)

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    Type
    Article
    Authors
    Davaasuren, Bambar cc
    Alahmary, Fatimah S. cc
    Dashjav, Enkhtsetseg
    Khanderi, Jayaprakash cc
    Rothenberger, Alexander
    KAUST Department
    Chemical Science Program
    Physical Science and Engineering (PSE) Division
    KAUST Grant Number
    BAS/1/1302–01–01
    Date
    2016-11-11
    Online Publication Date
    2016-11-11
    Print Publication Date
    2016-12
    Permanent link to this record
    http://hdl.handle.net/10754/622155
    
    Metadata
    Show full item record
    Abstract
    Ternary alkali metal thiobismuthates ABiS (A = K, Rb) were synthesized by direct combination reactions at 650 °C. The compounds crystallize in the monoclinic space group C2/m (no. 12) with cell parameters a = 30.919(1) Å, b = 4.1008(2) Å, c = 20.9072(9) Å, β = 105.826(3)° for KBiS (1) and a = 31.823(6) Å, b = 4.1177(8) Å, c = 21.086(4) Å, β = 105.62(3)° for RbBiS (2). The crystal structure of 1 contains a 3D [KBiS] polyanionic framework, whereas 2 consists of 2D [RbBiS] polyanionic slabs stacked along [201]. Both 1 and 2 are semiconductors with a band gap of 1.4 and 1.3 eV, respectively, which is supported by an electronic structure calculation. 1 melts congruently at 580 °C, while 2 melts incongruently at 575 °C. 1 and 2 are airstable and insoluble in water and organic solvents.
    Citation
    Davaasuren B, Alahmari F, Dashjav E, Khanderi J, Rothenberger A (2016) Synthesis and Characterization of the Ternary Thiobismuthates A9Bi13S24 (A = K, Rb). Zeitschrift für anorganische und allgemeine Chemie 642: 1480–1485. Available: http://dx.doi.org/10.1002/zaac.201600159.
    Sponsors
    This research was supported by King Abdullah University of Science and Technology (KAUST) baseline fund BAS/1/1302–01–01.
    Publisher
    Wiley
    Journal
    Zeitschrift für anorganische und allgemeine Chemie
    DOI
    10.1002/zaac.201600159
    Additional Links
    http://onlinelibrary.wiley.com/doi/10.1002/zaac.201600159/full
    Relations
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.25505/fiz.icsd.cc1y3swq HANDLE: 10754/663686
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.25505/fiz.icsd.cc1y2hgz HANDLE: 10754/663690
    ae974a485f413a2113503eed53cd6c53
    10.1002/zaac.201600159
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program

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