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dc.contributor.authorGuo, Lin
dc.contributor.authorRueping, Magnus
dc.date.accessioned2017-01-01T13:44:45Z
dc.date.available2017-01-01T13:44:45Z
dc.date.issued2016-10-11
dc.identifier.citationGuo L, Rueping M (2016) Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates. Chemistry - A European Journal 22: 16787–16790. Available: http://dx.doi.org/10.1002/chem.201604504.
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201604504
dc.identifier.urihttp://hdl.handle.net/10754/622118
dc.description.abstractA new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.
dc.description.sponsorshipL.G. was supported by the China Scholarship Council.
dc.publisherWiley
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/chem.201604504/abstract
dc.subjectC-H borylation
dc.subjectC-O bond activation
dc.subjectdecarbonylative cross-coupling
dc.subjectesters
dc.subjectnickel
dc.titleFunctional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - A European Journal
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen, Germany
kaust.personRueping, Magnus
dc.date.published-online2016-10-11
dc.date.published-print2016-11-14


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