Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates
Type
ArticleAuthors
Guo, LinRueping, Magnus

KAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2016-10-11Online Publication Date
2016-10-11Print Publication Date
2016-11-14Permanent link to this record
http://hdl.handle.net/10754/622118
Metadata
Show full item recordAbstract
A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.Citation
Guo L, Rueping M (2016) Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates. Chemistry - A European Journal 22: 16787–16790. Available: http://dx.doi.org/10.1002/chem.201604504.Sponsors
L.G. was supported by the China Scholarship Council.Publisher
WileyJournal
Chemistry - A European JournalAdditional Links
http://onlinelibrary.wiley.com/doi/10.1002/chem.201604504/abstractae974a485f413a2113503eed53cd6c53
10.1002/chem.201604504