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    Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates

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    Type
    Article
    Authors
    Guo, Lin
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-10-11
    Online Publication Date
    2016-10-11
    Print Publication Date
    2016-11-14
    Permanent link to this record
    http://hdl.handle.net/10754/622118
    
    Metadata
    Show full item record
    Abstract
    A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.
    Citation
    Guo L, Rueping M (2016) Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates. Chemistry - A European Journal 22: 16787–16790. Available: http://dx.doi.org/10.1002/chem.201604504.
    Sponsors
    L.G. was supported by the China Scholarship Council.
    Publisher
    Wiley
    Journal
    Chemistry - A European Journal
    DOI
    10.1002/chem.201604504
    Additional Links
    http://onlinelibrary.wiley.com/doi/10.1002/chem.201604504/abstract
    ae974a485f413a2113503eed53cd6c53
    10.1002/chem.201604504
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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