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    Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

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    Type
    Article
    Authors
    Fan, Lulu
    Jia, Jiaqi
    Hou, Hong
    Lefebvre, Quentin
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-10-10
    Online Publication Date
    2016-10-10
    Print Publication Date
    2016-11-07
    Permanent link to this record
    http://hdl.handle.net/10754/622116
    
    Metadata
    Show full item record
    Abstract
    A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.
    Citation
    Fan L, Jia J, Hou H, Lefebvre Q, Rueping M (2016) Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling. Chemistry - A European Journal 22: 16437–16440. Available: http://dx.doi.org/10.1002/chem.201604452.
    Sponsors
    The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 617044 (SunCatChem).
    Publisher
    Wiley
    Journal
    Chemistry - A European Journal
    DOI
    10.1002/chem.201604452
    Additional Links
    http://onlinelibrary.wiley.com/doi/10.1002/chem.201604452/abstract
    ae974a485f413a2113503eed53cd6c53
    10.1002/chem.201604452
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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