Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling
Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2016-10-10Online Publication Date
2016-10-10Print Publication Date
2016-11-07Permanent link to this record
http://hdl.handle.net/10754/622116
Metadata
Show full item recordAbstract
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.Citation
Fan L, Jia J, Hou H, Lefebvre Q, Rueping M (2016) Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling. Chemistry - A European Journal 22: 16437–16440. Available: http://dx.doi.org/10.1002/chem.201604452.Sponsors
The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 617044 (SunCatChem).Publisher
WileyJournal
Chemistry - A European JournalAdditional Links
http://onlinelibrary.wiley.com/doi/10.1002/chem.201604452/abstractae974a485f413a2113503eed53cd6c53
10.1002/chem.201604452