Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases
Sheikh, Arif D.
El Tall, Omar
Smilgies, Detlef M.
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AbstractSolution-processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one-step spin-coating process of perovskites is investigated in situ, revealing that thin-film formation is mediated by solid-state precursor solvates and their nature. The stability of these intermediate phases directly impacts the quality and reproducibility of thermally converted perovskite films and their photovoltaic performance.
CitationMunir R, Sheikh AD, Abdelsamie M, Hu H, Yu L, et al. (2016) Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases. Advanced Materials. Available: http://dx.doi.org/10.1002/adma.201604113.
SponsorsThis work was supported by the Office of Competitive Research Funds under the Competitive Research Grant (round 1) and Academic Excellence Alliance (round 3). CHESS is supported by the NSF & NIH/NIGMS via NSF award DMR-1332208. A.A. is grateful to SABIC for the Career Development SABIC Chair. The authors are thankful to Heno Hwang for using his artistic abilities to design Figure 4 of this report.