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dc.contributor.authorHaque, Mohammed
dc.contributor.authorDavaasuren, Bambar
dc.contributor.authorRothenberger, Alexander
dc.contributor.authorWu, Tao
dc.date.accessioned2016-12-22T13:34:56Z
dc.date.available2016-12-22T13:34:56Z
dc.date.issued2016-11-15
dc.identifier.citationHaque MA, Davaasuren B, Rothenberger A, Wu T (2016) Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide. Acta Crystallographica Section E Crystallographic Communications 72: 1791–1793. Available: http://dx.doi.org/10.1107/S2056989016017904.
dc.identifier.issn2056-9890
dc.identifier.doi10.1107/S2056989016017904
dc.identifier.urihttp://hdl.handle.net/10754/622059
dc.description.abstractThe title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.
dc.description.sponsorshipThis work was supported by the King Abdullah University of Science and Technology (KAUST).
dc.publisherInternational Union of Crystallography (IUCr)
dc.relation.urlhttp://scripts.iucr.org/cgi-bin/paper?S2056989016017904
dc.rightsArchived with thanks to Acta Crystallographica Section E: Crystallographic Communications. Under the Creative Commons Attribution License
dc.subjectcrystal structure
dc.subjectisotypism
dc.subjectoctahedral coordination
dc.subjecttetraiodide
dc.titleCrystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide
dc.typeArticle
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalActa Crystallographica Section E Crystallographic Communications
dc.eprint.versionPublisher's Version/PDF
kaust.personHaque, Mohammed
kaust.personDavaasuren, Bambar
kaust.personRothenberger, Alexander
kaust.personWu, Tao
dc.relation.isSupplementedByHaque, M. A., Davaasuren, B., Rothenberger, A., & Wu, T. (2016). CCDC 1515632: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1mw4c0
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.cc1mw4c0
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624597
refterms.dateFOA2018-06-13T14:44:51Z


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