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    Living Polycondensation: Synthesis of Well-Defined Aromatic Polyamide-Based Polymeric Materials

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    Name:
    Mram's thesis F.pdf
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    5.815Mb
    Format:
    PDF
    Description:
    Living Polycondensation
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    Type
    Thesis
    Authors
    Alyami, Mram Z. cc
    Advisors
    Hadjichristidis, Nikos cc
    Committee members
    Rodionov, Valentin cc
    Nunes, Suzana Pereira cc
    Program
    Chemical Science
    KAUST Department
    Physical Science and Engineering (PSE) Division
    Date
    2016-11
    Embargo End Date
    2017-11-24
    Permanent link to this record
    http://hdl.handle.net/10754/621874
    
    Metadata
    Show full item record
    Access Restrictions
    At the time of archiving, the student author of this thesis opted to temporarily restrict access to it. The full text of this thesis became available to the public after the expiration of the embargo on 2017-11-24.
    Abstract
    Chain growth condensation polymerization is a powerful tool towards the synthesis of well-defined polyamides. This thesis focuses on one hand, on the synthesis of well-defined aromatic polyamides with different aminoalkyl pendant groups with low polydispersity and controlled molecular weights, and on the other hand, on studying their thermal properties. In the first project, well-defined poly (N-octyl-p-aminobenzoate) and poly (N-butyl-p-aminobenzoate) were synthesized, and for the first time, their thermal properties were studied. In the second project, ethyl4-aminobenzoate, ethyl 4-octyl aminobenzoate and 4-(hydroxymethyl) benzoic acid were used as novel efficient initiators of ε-caprolactone with t-BuP2 as a catalyst. Macroinitiator and Macromonomer of poly (ε-caprolactone) were synthesized with ethyl 4-octyl aminobenzoate and ethyl 4-aminobenzoate as initiators to afford polyamide-block-poly (ε-caprolactone) and polyamide-graft-poly (ε-caprolactone) by chain growth condensation polymerization (CGCP). In the third project, a new study has been done on chain growth condensation polymerization to discover the probability to synthesize new polymers and studied their thermal properties. For this purpose, poly (N-cyclohexyl-p-aminobenzoate) and poly (N-hexyl-p-aminobenzoate) were synthesized with low polydispersity and controlled molecular weights.
    Citation
    Alyami, M. Z. (2016). Living Polycondensation: Synthesis of Well-Defined Aromatic Polyamide-Based Polymeric Materials. KAUST Research Repository. https://doi.org/10.25781/KAUST-1SQ9U
    DOI
    10.25781/KAUST-1SQ9U
    ae974a485f413a2113503eed53cd6c53
    10.25781/KAUST-1SQ9U
    Scopus Count
    Collections
    MS Theses; Physical Science and Engineering (PSE) Division; Chemical Science Program

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