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dc.contributor.authorSarathy, Mani
dc.contributor.authorKukkadapu, Goutham
dc.contributor.authorMehl, Marco
dc.contributor.authorJaved, Tamour
dc.contributor.authorAhmed, Ahfaz
dc.contributor.authorNaser, Nimal
dc.contributor.authorTekawade, Aniket
dc.contributor.authorKosiba, Graham
dc.contributor.authorAlAbbad, Mohammed A.
dc.contributor.authorSingh, Eshan
dc.contributor.authorPark, Sungwoo
dc.contributor.authorRashidi, Mariam Al
dc.contributor.authorChung, Suk Ho
dc.contributor.authorRoberts, William L.
dc.contributor.authorOehlschlaeger, Matthew A.
dc.contributor.authorSung, Chih-Jen
dc.contributor.authorFarooq, Aamir
dc.date.accessioned2016-11-03T13:23:48Z
dc.date.available2016-11-03T13:23:48Z
dc.date.issued2016-05-08
dc.identifier.citationSarathy SM, Kukkadapu G, Mehl M, Javed T, Ahmed A, et al. (2016) Compositional effects on the ignition of FACE gasolines. Combustion and Flame 169: 171–193. Available: http://dx.doi.org/10.1016/j.combustflame.2016.04.010.
dc.identifier.issn0010-2180
dc.identifier.doi10.1016/j.combustflame.2016.04.010
dc.identifier.urihttp://hdl.handle.net/10754/621733
dc.description.abstractAs regulatory measures for improved fuel economy and decreased emissions are pushing gasoline engine combustion technologies towards extreme conditions (i.e., boosted and intercooled intake with exhaust gas recirculation), fuel ignition characteristics become increasingly important for enabling stable operation. This study explores the effects of chemical composition on the fundamental ignition behavior of gasoline fuels. Two well-characterized, high-octane, non-oxygenated FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G, having similar antiknock indices but different octane sensitivities and chemical compositions are studied. Ignition experiments were conducted in shock tubes and a rapid compression machine (RCM) at nominal pressures of 20 and 40. atm, equivalence ratios of 0.5 and 1.0, and temperatures ranging from 650 to 1270. K. Results at temperatures above 900. K indicate that ignition delay time is similar for these fuels. However, RCM measurements below 900. K demonstrate a stronger negative temperature coefficient behavior for FACE F gasoline having lower octane sensitivity. In addition, RCM pressure profiles under two-stage ignition conditions illustrate that the magnitude of low-temperature heat release (LTHR) increases with decreasing fuel octane sensitivity. However, intermediate-temperature heat release is shown to increase as fuel octane sensitivity increases. Various surrogate fuel mixtures were formulated to conduct chemical kinetic modeling, and complex multicomponent surrogate mixtures were shown to reproduce experimentally observed trends better than simpler two- and three-component mixtures composed of n-heptane, iso-octane, and toluene. Measurements in a Cooperative Fuels Research (CFR) engine demonstrated that the multicomponent surrogates accurately captured the antiknock quality of the FACE gasolines. Simulations were performed using multicomponent surrogates for FACE F and G to reveal the underlying chemical kinetics linking fuel composition with ignition characteristics. A key discovery of this work is the kinetic coupling between aromatics and naphthenes, which affects the radical pool population and thereby controls ignition. © 2016 The Combustion Institute.
dc.description.sponsorshipThe authors are grateful to Hendrik Muller (Saudi Aramco R&DC), Jihad Badra (Saudi Aramco R&DC), Abdulla Algam (Saudi Aramco R&DC), Emad Alawi (Saudi Aramco R&DC), and Nadim Hourani (KAUST) for the DHA results. The KAUST authors acknowledge funding support from the Clean Combustion Research Center and from Saudi Aramco under the FUELCOM program. The work at the University of Connecticut was supported by the National Science Foundation under Grant No. CBET-1402231. The Rensselaer group was supported by the U.S. Air Force Office of Scientific Research (Grant No. FA9550-11-1-0261) with Dr. Chiping Li as technical monitor. The LLNL work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under Contract DE- AC52-07NA27344 and was supported by the U.S. Department of Energy, Office of Vehicle Technologies, Gurpreet Singh, program manager.
dc.publisherElsevier BV
dc.subjectChemical kinetic modeling
dc.subjectIgnition
dc.subjectOctane number
dc.subjectRapid compression machine
dc.subjectShock tube
dc.subjectSurrogate fuels
dc.titleCompositional effects on the ignition of FACE gasolines
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Kinetics & Laser Sensors Laboratory
dc.contributor.departmentClean Combustion Research Center
dc.contributor.departmentCombustion and Laser Diagnostics Laboratory
dc.contributor.departmentCombustion and Pyrolysis Chemistry (CPC) Group
dc.contributor.departmentMechanical Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmenthigh-pressure combustion (HPC) Research Group
dc.identifier.journalCombustion and Flame
dc.contributor.institutionDepartment of Mechanical Engineering, University of Connecticut, Storrs, CT, United States
dc.contributor.institutionLawrence Livermore National Laboratory, Livermore, CA, United States
dc.contributor.institutionMechanical, Aerospace, and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY, United States
kaust.personSarathy, Mani
kaust.personJaved, Tamour
kaust.personAhmed, Ahfaz
kaust.personNaser, Nimal
kaust.personAlabbad, Mohammed
kaust.personSingh, Eshan
kaust.personPark, Sungwoo
kaust.personRashidi, Mariam Al
kaust.personChung, Suk Ho
kaust.personRoberts, William L.
kaust.personFarooq, Aamir
kaust.acknowledged.supportUnitClean Combustion Research Center
dc.date.published-online2016-05-08
dc.date.published-print2016-07


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