Synthesis, Structure and Catalytic Activity of NHC-AgICarboxylate Complexes
Type
ArticleAuthors
Wong, Valerie H. L.Vummaleti, Sai V. C.

Cavallo, Luigi

White, Andrew J. P.
Nolan, Steven P.

Hii, King Kuok Mimi

KAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2016-08-02Online Publication Date
2016-08-02Print Publication Date
2016-09-05Permanent link to this record
http://hdl.handle.net/10754/621714
Metadata
Show full item recordAbstract
A general synthetic route was used to prepare 15 new N-heterocyclic carbene (NHC)–AgI complexes bearing anionic carboxylate ligands [Ag(NHC)(O2CR)], including a homologous series of complexes of sterically flexible ITent ligands, which permit a systematic spectroscopic and theoretical study of the structural and electronic features of these compounds. The complexes displayed a significant ligand-accelerated effect in the intramolecular cyclisation of propargylic amides to oxazolidines. The substrate scope is highly complementary to that previously achieved by NHC–Au and pyridyl–AgI complexes. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimCitation
Wong VHL, Vummaleti SVC, Cavallo L, White AJP, Nolan SP, et al. (2016) Synthesis, Structure and Catalytic Activity of NHC-AgICarboxylate Complexes. Chemistry - A European Journal 22: 13320–13327. Available: http://dx.doi.org/10.1002/chem.201601762.Sponsors
The authors are grateful to NUS and the Imperial College London for the award of a scholarship (to V.H.L.W.). L.C. and S.P.N. thank the KAUST for support through the CCF project.Publisher
WileyJournal
Chemistry - A European JournalPubMed ID
27483036Relations
Is Supplemented By:- [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449329: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4kx. DOI: 10.5517/ccdc.csd.cc1kn4kx HANDLE: 10754/624559 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449330: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4ly. DOI: 10.5517/ccdc.csd.cc1kn4ly HANDLE: 10754/624560 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449331: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4mz. DOI: 10.5517/ccdc.csd.cc1kn4mz HANDLE: 10754/624561 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449332: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4n0. DOI: 10.5517/ccdc.csd.cc1kn4n0 HANDLE: 10754/624562 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449337: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4t5. DOI: 10.5517/ccdc.csd.cc1kn4t5 HANDLE: 10754/624567 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449338: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4v6. DOI: 10.5517/ccdc.csd.cc1kn4v6 HANDLE: 10754/624568 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449339: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4w7. DOI: 10.5517/ccdc.csd.cc1kn4w7 HANDLE: 10754/624569 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449340: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4x8. DOI: 10.5517/ccdc.csd.cc1kn4x8 HANDLE: 10754/624570 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449341: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4y9. DOI: 10.5517/ccdc.csd.cc1kn4y9 HANDLE: 10754/624571 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449342: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4zb. DOI: 10.5517/ccdc.csd.cc1kn4zb HANDLE: 10754/624572 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449343: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn50d. DOI: 10.5517/ccdc.csd.cc1kn50d HANDLE: 10754/624573 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449333: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4p1. DOI: 10.5517/ccdc.csd.cc1kn4p1 HANDLE: 10754/624563 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449334: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4q2. DOI: 10.5517/ccdc.csd.cc1kn4q2 HANDLE: 10754/624564 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449335: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4r3. DOI: 10.5517/ccdc.csd.cc1kn4r3 HANDLE: 10754/624565 - [Dataset]
Wong, V. H. L., Vummaleti, S. V. C., Cavallo, L., White, A. J. P., Nolan, S. P., & Hii, K. K. (2016). CCDC 1449336: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1kn4s4. DOI: 10.5517/ccdc.csd.cc1kn4s4 HANDLE: 10754/624566
ae974a485f413a2113503eed53cd6c53
10.1002/chem.201601762
Scopus Count
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