Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide

Type
Article
Authors
Wang, De cc
Zhang, Zhen
Hadjichristidis, Nikolaos cc
KAUST Department
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Polymer Synthesis Laboratory
Date
2016-03-01
Permanent link to this record
http://hdl.handle.net/10754/621694

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Abstract
A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.
Citation
Wang D, Zhang Z, Hadjichristidis N (2016) Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide. ACS Macro Letters 5: 387–390. Available: http://dx.doi.org/10.1021/acsmacrolett.6b00082.
Sponsors
Research reported in this publication was supported by the King Abdullah University of Science and Technology.
Publisher
American Chemical Society (ACS)
Journal
ACS Macro Letters
ISSN
2161-1653
2161-1653
DOI
10.1021/acsmacrolett.6b00082
Additional Links
http://pubs.acs.org/doi/abs/10.1021/acsmacrolett.6b00082
Collections
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)