Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide
KAUST DepartmentKAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Polymer Synthesis Laboratory
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AbstractA novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.
CitationWang D, Zhang Z, Hadjichristidis N (2016) Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide. ACS Macro Letters 5: 387–390. Available: http://dx.doi.org/10.1021/acsmacrolett.6b00082.
SponsorsResearch reported in this publication was supported by the King Abdullah University of Science and Technology.
PublisherAmerican Chemical Society (ACS)
JournalACS Macro Letters