Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide
Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Polymer Synthesis Laboratory
Date
2016-03Online Publication Date
2016-03Print Publication Date
2016-03-15Permanent link to this record
http://hdl.handle.net/10754/621694
Metadata
Show full item recordAbstract
A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.Citation
Wang D, Zhang Z, Hadjichristidis N (2016) Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide. ACS Macro Letters 5: 387–390. Available: http://dx.doi.org/10.1021/acsmacrolett.6b00082.Sponsors
Research reported in this publication was supported by the King Abdullah University of Science and Technology.Publisher
American Chemical Society (ACS)Journal
ACS Macro LettersAdditional Links
http://pubs.acs.org/doi/abs/10.1021/acsmacrolett.6b00082ae974a485f413a2113503eed53cd6c53
10.1021/acsmacrolett.6b00082