Well-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis
| dc.contributor.author | Hamzaoui, Bilel | |
| dc.contributor.author | Pelletier, Jeremie | |
| dc.contributor.author | Abou-Hamad, Edy | |
| dc.contributor.author | Basset, Jean-Marie | |
| dc.date.accessioned | 2016-11-03T13:22:49Z | |
| dc.date.available | 2016-11-03T13:22:49Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Hamzaoui B, Pelletier JDA, Abou-Hamad E, Basset J-M (2016) Well-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis. Chem Commun 52: 4617–4620. Available: http://dx.doi.org/10.1039/c6cc00471g. | |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.issn | 1364-548X | |
| dc.identifier.pmid | 26903397 | |
| dc.identifier.doi | 10.1039/c6cc00471g | |
| dc.identifier.uri | http://hdl.handle.net/10754/621689 | |
| dc.description.abstract | Upon prolonged thermal exposure under vacuum, a well-defined single-site surface species [(≡Si-O-)Zr(NEt2)3] (1) evolves into an ethylimido complex [(≡Si-O-)Zr(=NEt)NEt2] (2). Reactions of 2 with an imine substrate result in imido/imine (=NRi, R: Et, Ph) exchange (metathesis) with the formation of [(≡Si-O-)Zr(=NPh)NEt2] (3). Compounds 2 and 3 effectively catalyze imine/imine cross-metathesis and are thus considered as the first heterogeneous catalysts active for imine metathesis. © The Royal Society of Chemistry 2016. | |
| dc.publisher | Royal Society of Chemistry (RSC) | |
| dc.title | Well-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis | |
| dc.type | Article | |
| dc.contributor.department | Chemical Science Program | |
| dc.contributor.department | KAUST Catalysis Center (KCC) | |
| dc.identifier.journal | Chemical Communications | |
| kaust.person | Hamzaoui, Bilel | |
| kaust.person | Pelletier, Jeremie | |
| kaust.person | Abou-Hamad, Edy | |
| kaust.person | Basset, Jean-Marie |