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dc.contributor.authorHamzaoui, Bilel
dc.contributor.authorPelletier, Jeremie
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2016-11-03T13:22:49Z
dc.date.available2016-11-03T13:22:49Z
dc.date.issued2016
dc.identifier.citationHamzaoui B, Pelletier JDA, Abou-Hamad E, Basset J-M (2016) Well-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis. Chem Commun 52: 4617–4620. Available: http://dx.doi.org/10.1039/c6cc00471g.
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.pmid26903397
dc.identifier.doi10.1039/c6cc00471g
dc.identifier.urihttp://hdl.handle.net/10754/621689
dc.description.abstractUpon prolonged thermal exposure under vacuum, a well-defined single-site surface species [(≡Si-O-)Zr(NEt2)3] (1) evolves into an ethylimido complex [(≡Si-O-)Zr(=NEt)NEt2] (2). Reactions of 2 with an imine substrate result in imido/imine (=NRi, R: Et, Ph) exchange (metathesis) with the formation of [(≡Si-O-)Zr(=NPh)NEt2] (3). Compounds 2 and 3 effectively catalyze imine/imine cross-metathesis and are thus considered as the first heterogeneous catalysts active for imine metathesis. © The Royal Society of Chemistry 2016.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleWell-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalChemical Communications
kaust.personHamzaoui, Bilel
kaust.personPelletier, Jeremie
kaust.personAbou-Hamad, Edy
kaust.personBasset, Jean-Marie


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