Solid-State NMR and DFT Studies on the Formation of Well-Defined Silica-Supported Tantallaaziridines: From Synthesis to Catalytic Application
El Eter, Mohamad
KAUST DepartmentChemical Science Program
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Physical Science and Engineering (PSE) Division
Online Publication Date2016-01-27
Print Publication Date2016-02-24
Permanent link to this recordhttp://hdl.handle.net/10754/621685
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AbstractSingle-site, well-defined, silica-supported tantallaaziridine intermediates [≡Si-O-Ta(η2-NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [≡Si-O-Ta(NMe2)4] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and 1H,13C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by β-H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
CitationHamzaoui B, Pelletier JDA, Abou-Hamad E, Chen Y, El Eter M, et al. (2016) Solid-State NMR and DFT Studies on the Formation of Well-Defined Silica-Supported Tantallaaziridines: From Synthesis to Catalytic Application. Chem Eur J 22: 3000–3008. Available: http://dx.doi.org/10.1002/chem.201504439.
SponsorsThe authors wish to thank King Abdullah University of Science and Technology for continuous support.
JournalChemistry - A European Journal
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