Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
KAUST DepartmentKAUST Catalysis Center (KCC)
Permanent link to this recordhttp://hdl.handle.net/10754/621678
MetadataShow full item record
AbstractConspectusHeterogeneous catalysis, a field important industrially and scientifically, is increasingly seeking and refining strategies to render itself more predictable. The main issue is due to the nature and the population of catalytically active sites. Their number is generally low to very low, their "acid strengths" or " redox properties" are not homogeneous, and the material may display related yet inactive sites on the same material. In many heterogeneous catalysts, the discovery of a structure-activity reationship is at best challenging. One possible solution is to generate single-site catalysts in which most, if not all, of the sites are structurally identical. Within this context and using the right tools, the catalyst structure can be designed and well-defined, to reach a molecular understanding. It is then feasible to understand the structure-activity relationship and to develop predictable heterogeneous catalysis. Single-site well-defined heterogeneous catalysts can be prepared using concepts and tools of surface organometallic chemistry (SOMC). This approach operates by reacting organometallic compounds with surfaces of highly divided oxides (or of metal nanoparticles). This strategy has a solid track record to reveal structure-activity relationship to the extent that it is becoming now quite predictable. Almost all elements of the periodical table have been grafted on surfaces of oxides (from simple oxides such as silica or alumina to more sophisticated materials regarding composition or porosity).Considering catalytic hydrocarbon transformations, heterogeneous catalysis outcome may now be predicted based on existing mechanistic proposals and the rules of molecular chemistry (organometallic, organic) associated with some concepts of surface sciences. A thorough characterization of the grafted metal centers must be carried out using tools spanning from molecular organometallic or surface chemistry. By selection of the metal, its ligand set, and the support taken as a X, L ligands in the Green formalism, the catalyst can be designed and generated by grafting the organometallic precursor containing the functional group(s) suitable to target a given transformation (surface organometallic fragments (SOMF)). The choice of these SOMF is based on the elementary steps known in molecular chemistry applied to the desired reaction. The coordination sphere necessary for any catalytic reaction involving paraffins, olefins, and alkynes also can thus be predicted. Only their most complete understanding can allow development of catalytic reactions with the highest possible selectivity, activity, and lifetime. This Account will examine the results of SOMC for hydrocarbon transformations on oxide surfaces bearing metals of group 4-6. The silica-supported catalysts are exhibiting remarkable performances for Ziegler-Natta polymerization and depolymerization, low temperature hydrogenolysis of alkanes and waxes, metathesis of alkanes and cycloalkanes, olefins metathesis, and related reactions. In the case of reactions involving molecules that do not contain carbon (water-gas shift, NH3 synthesis, etc.) this single site approach is also valid but will be considered in a later review. © 2016 American Chemical Society.
CitationPelletier JDA, Basset J-M (2016) Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts. Acc Chem Res 49: 664–677. Available: http://dx.doi.org/10.1021/acs.accounts.5b00518.
SponsorsWe thank KAUST for financial and human support and all our friends who helped us to develop this field and continue to do so in Europe, China, Japan, the Americas, and the Middle East including Saudi Arabia.
PublisherAmerican Chemical Society (ACS)
JournalAccounts of Chemical Research
- Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry.
- Authors: Copéret C, Chabanas M, Petroff Saint-Arroman R, Basset JM
- Issue date: 2003 Jan 13
- Surface organometallic chemistry in heterogeneous catalysis.
- Authors: Samantaray MK, Pump E, Bendjeriou-Sedjerari A, D'Elia V, Pelletier JDA, Guidotti M, Psaro R, Basset JM
- Issue date: 2018 Nov 12
- Multinuclear group 4 catalysis: olefin polymerization pathways modified by strong metal-metal cooperative effects.
- Authors: McInnis JP, Delferro M, Marks TJ
- Issue date: 2014 Aug 19
- Unique properties of ceria nanoparticles supported on metals: novel inverse ceria/copper catalysts for CO oxidation and the water-gas shift reaction.
- Authors: Senanayake SD, Stacchiola D, Rodriguez JA
- Issue date: 2013 Aug 20
- Site Isolation in Metal-Organic Frameworks Enables Novel Transition Metal Catalysis.
- Authors: Drake T, Ji P, Lin W
- Issue date: 2018 Sep 18