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    Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation

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    Type
    Article
    Authors
    Guo, Lin
    Hsiao, Chien-Chi
    Yue, Huifeng
    Liu, Xiangqian
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-06-13
    Online Publication Date
    2016-06-13
    Print Publication Date
    2016-07
    Permanent link to this record
    http://hdl.handle.net/10754/621676
    
    Metadata
    Show full item record
    Abstract
    A new and efficient nickel-catalyzed alkylation of CAr-O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various Csp2-Csp3 bonds through Csp2-O substitution, without the restriction of β-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C-O bond activation process. © 2016 American Chemical Society.
    Citation
    Guo L, Hsiao C-C, Yue H, Liu X, Rueping M (2016) Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation . ACS Catalysis 6: 4438–4442. Available: http://dx.doi.org/10.1021/acscatal.6b00801.
    Sponsors
    L.G., H.Y., and X.L. gratefully acknowledge the China Scholarship Council. C.-C.H. gratefully acknowledges DAAD for fellowship.
    Publisher
    American Chemical Society (ACS)
    Journal
    ACS Catalysis
    DOI
    10.1021/acscatal.6b00801
    ae974a485f413a2113503eed53cd6c53
    10.1021/acscatal.6b00801
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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