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dc.contributor.authorLuo, Xiaolong
dc.contributor.authorCao, Yu
dc.contributor.authorWang, Tao
dc.contributor.authorLi, Guanghua
dc.contributor.authorLi, Jiangang
dc.contributor.authorYang, Yonggang
dc.contributor.authorXu, Zhongxuan
dc.contributor.authorZhang, Jian
dc.contributor.authorHuo, Qisheng
dc.contributor.authorLiu, Yunling
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2016-11-03T13:22:27Z
dc.date.available2016-11-03T13:22:27Z
dc.date.issued2016-01-12
dc.identifier.citationLuo X, Cao Y, Wang T, Li G, Li J, et al. (2016) Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests. Journal of the American Chemical Society 138: 786–789. Available: http://dx.doi.org/10.1021/jacs.5b12516.
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.pmid26754145
dc.identifier.doi10.1021/jacs.5b12516
dc.identifier.urihttp://hdl.handle.net/10754/621673
dc.description.abstractA novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.
dc.description.sponsorshipThe authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/jacs.5b12516
dc.titleHost–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, China
dc.contributor.institutionJiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry Chemical Engineering and Materials Science, Soochow University, Suzhou, China
dc.contributor.institutionState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
kaust.personEddaoudi, Mohamed
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410364: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblm2
dc.relation.isSupplementedByDOI:10.5517/cc1jblm2
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624444
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410365: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jbln3
dc.relation.isSupplementedByDOI:10.5517/cc1jbln3
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624445
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410366: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblp4
dc.relation.isSupplementedByDOI:10.5517/cc1jblp4
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624446


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