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    Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

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    Type
    Article
    Authors
    Luo, Xiaolong
    Cao, Yu
    Wang, Tao
    Li, Guanghua cc
    Li, Jiangang
    Yang, Yonggang
    Xu, Zhongxuan
    Zhang, Jian
    Huo, Qisheng
    Liu, Yunling cc
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2016-01-14
    Online Publication Date
    2016-01-14
    Print Publication Date
    2016-01-27
    Permanent link to this record
    http://hdl.handle.net/10754/621673
    
    Metadata
    Show full item record
    Abstract
    A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.
    Citation
    Luo X, Cao Y, Wang T, Li G, Li J, et al. (2016) Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests. Journal of the American Chemical Society 138: 786–789. Available: http://dx.doi.org/10.1021/jacs.5b12516.
    Sponsors
    The authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/jacs.5b12516
    PubMed ID
    26754145
    Additional Links
    http://pubs.acs.org/doi/abs/10.1021/jacs.5b12516
    Relations
    Is Supplemented By:
    • [Dataset]
      Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410364: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblm2. DOI: 10.5517/cc1jblm2 HANDLE: 10754/624444
    • [Dataset]
      Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410365: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jbln3. DOI: 10.5517/cc1jbln3 HANDLE: 10754/624445
    • [Dataset]
      Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410366: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblp4. DOI: 10.5517/cc1jblp4 HANDLE: 10754/624446
    ae974a485f413a2113503eed53cd6c53
    10.1021/jacs.5b12516
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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