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    Controlled growth of high-density CdS and CdSe nanorod arrays on selective facets of two-dimensional semiconductor nanoplates

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    Type
    Article
    Authors
    Wu, Xue-Jun
    Chen, Junze
    Tan, Chaoliang
    Zhu, Yihan
    Han, Yu cc
    Zhang, Hua cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Nanostructured Functional Materials (NFM) laboratory
    Physical Science and Engineering (PSE) Division
    Date
    2016-03-14
    Online Publication Date
    2016-03-14
    Print Publication Date
    2016-05
    Permanent link to this record
    http://hdl.handle.net/10754/621663
    
    Metadata
    Show full item record
    Abstract
    The rational synthesis of hierarchical three-dimensional nanostructures with specific compositions, morphologies and functionalities is important for applications in a variety of fields ranging from energy conversion and electronics to biotechnology. Here, we report a seeded growth approach for the controlled epitaxial growth of three types of hierarchical one-dimensional (1D)/two-dimensional (2D) nanostructures, where nanorod arrays of II-VI semiconductor CdS or CdSe are grown on the selective facets of hexagonal-shaped nanoplates, either on the two basal facets of the nanoplate, or on one basal facet, or on the two basal facets and six side facets. The seed engineering of 2D hexagonal-shaped nanoplates is the key factor for growth of the three resulting types of 1D/2D nanostructures. The wurtzite- and zinc-blende-type polymorphs of semiconductors are used to determine the facet-selective epitaxial growth of 1D nanorod arrays, resulting in the formation of different hierarchical three-dimensional (3D) nanostructures. © 2016 Macmillan Publishers Limited. All rights reserved.
    Citation
    Wu X-J, Chen J, Tan C, Zhu Y, Han Y, et al. (2016) Controlled growth of high-density CdS and CdSe nanorod arrays on selective facets of two-dimensional semiconductor nanoplates. Nature Chem 8: 470–475. Available: http://dx.doi.org/10.1038/nchem.2473.
    Sponsors
    This work was supported by Ministry of Education (MOE) under AcRF Tier 2 (ARC 26/13, no. MOE2013-T2-1-034; ARC 19/15, no. MOE2014-T2-2-093) and AcRF Tier 1 (RGT18/13, RG5/13), and Nanyang Technological University (NTU) under a start-up grant (M4081296.070.500000) in Singapore. Research was also conducted by the NTU-HUJ-BGU Nanomaterials for Energy and Water Management Programme at the Campus for Research Excellence and Technological Enterprise (CREATE), which is supported by the National Research Foundation of the Prime Minister's Office, Singapore. Y.H. thanks the King Abdullah University of Science and Technology for the baseline (BAS/1/1372-01-01) and CCF (FCC/1/1972-03-01) research grants.
    Publisher
    Springer Nature
    Journal
    Nature Chemistry
    DOI
    10.1038/nchem.2473
    PubMed ID
    27102681
    ae974a485f413a2113503eed53cd6c53
    10.1038/nchem.2473
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program

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