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dc.contributor.authorPan, Yupeng
dc.contributor.authorPan, Cheng-Ling
dc.contributor.authorZhang, Yufan
dc.contributor.authorLi, Huaifeng
dc.contributor.authorMin, Shixiong
dc.contributor.authorGuo, Xunmun
dc.contributor.authorZheng, Bin
dc.contributor.authorChen, Hailong
dc.contributor.authorAnders, Addison
dc.contributor.authorLai, Zhiping
dc.contributor.authorZheng, Junrong
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2016-11-03T08:32:31Z
dc.date.available2016-11-03T08:32:31Z
dc.date.issued2016-04-21
dc.identifier.citationPan, Y., Pan, C.-L., Zhang, Y., Li, H., Min, S., Guo, X., … Huang, K.-W. (2016). Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand. Chemistry - An Asian Journal, 11(9), 1357–1360. doi:10.1002/asia.201600169
dc.identifier.issn1861-4728
dc.identifier.pmid27101381
dc.identifier.doi10.1002/asia.201600169
dc.identifier.urihttp://hdl.handle.net/10754/621577
dc.description.abstractAn unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. Grabbing hold: A PN3-pincer complex was employed for the selective hydrogen generation from formic acid. Mechanistic studies suggest the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.
dc.description.sponsorshipK.-W.H. acknowledges the financial support from KAUST and a SABIC Chair Professorship. J.Z. thanks the supports from NSF (CHE-1503865), the Welch foundation under Award No. C-1752, Packard fellowship, and Sloan fellowship. Y.Z. thanks a Schlumberger future faculty award.
dc.publisherWiley
dc.relation.urlhttp://doi.wiley.com/10.1002/asia.201600169
dc.relation.urlhttps://rss.onlinelibrary.wiley.com/doi/am-pdf/10.1002/asia.201600169
dc.rightsArchived with thanks to Wiley
dc.rightsThis file is an open access version redistributed from: https://rss.onlinelibrary.wiley.com/doi/am-pdf/10.1002/asia.201600169
dc.subjectformic acid
dc.subjecthomogeneous catalysis
dc.subjecthydrogen
dc.subjectpincer ligands
dc.subjectruthenium
dc.titleSelective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - An Asian Journal
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry; Rice University; Houston TX 77005 USA
dc.identifier.volume11
dc.identifier.issue9
dc.identifier.pages1357-1360
kaust.personPan, Yupeng
kaust.personPan, Chengling
kaust.personLi, Huaifeng
kaust.personMin, Shixiong
kaust.personZheng, Bin
kaust.personLai, Zhiping
kaust.personHuang, Kuo-Wei
dc.identifier.eid2-s2.0-84966377299
refterms.dateFOA2021-06-16T11:50:49Z
dc.date.published-online2016-04-21
dc.date.published-print2016-05-06


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