Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand
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ArticleAuthors
Pan, YupengPan, Cheng-Ling
Zhang, Yufan
Li, Huaifeng
Min, Shixiong
Guo, Xunmun
Zheng, Bin
Chen, Hailong
Anders, Addison
Lai, Zhiping
Zheng, Junrong
Huang, Kuo-Wei
KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Engineering Program
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2016-04-21Online Publication Date
2016-04-21Print Publication Date
2016-05-06Permanent link to this record
http://hdl.handle.net/10754/621577
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An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. Grabbing hold: A PN3-pincer complex was employed for the selective hydrogen generation from formic acid. Mechanistic studies suggest the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.Citation
Pan, Y., Pan, C.-L., Zhang, Y., Li, H., Min, S., Guo, X., … Huang, K.-W. (2016). Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand. Chemistry - An Asian Journal, 11(9), 1357–1360. doi:10.1002/asia.201600169Sponsors
K.-W.H. acknowledges the financial support from KAUST and a SABIC Chair Professorship. J.Z. thanks the supports from NSF (CHE-1503865), the Welch foundation under Award No. C-1752, Packard fellowship, and Sloan fellowship. Y.Z. thanks a Schlumberger future faculty award.Publisher
WileyJournal
Chemistry – An Asian JournalPubMed ID
27101381Additional Links
http://doi.wiley.com/10.1002/asia.201600169https://rss.onlinelibrary.wiley.com/doi/am-pdf/10.1002/asia.201600169
ae974a485f413a2113503eed53cd6c53
10.1002/asia.201600169
Scopus Count
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