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    Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand

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    Selective...asia.201600169.pdf
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    Description:
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    Type
    Article
    Authors
    Pan, Yupeng
    Pan, Cheng-Ling
    Zhang, Yufan
    Li, Huaifeng
    Min, Shixiong
    Guo, Xunmun
    Zheng, Bin
    Chen, Hailong
    Anders, Addison
    Lai, Zhiping
    Zheng, Junrong
    Huang, Kuo-Wei
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Engineering Program
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-04-21
    Online Publication Date
    2016-04-21
    Print Publication Date
    2016-05-06
    Permanent link to this record
    http://hdl.handle.net/10754/621577
    
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    Abstract
    An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved. Grabbing hold: A PN3-pincer complex was employed for the selective hydrogen generation from formic acid. Mechanistic studies suggest the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.
    Citation
    Pan, Y., Pan, C.-L., Zhang, Y., Li, H., Min, S., Guo, X., … Huang, K.-W. (2016). Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand. Chemistry - An Asian Journal, 11(9), 1357–1360. doi:10.1002/asia.201600169
    Sponsors
    K.-W.H. acknowledges the financial support from KAUST and a SABIC Chair Professorship. J.Z. thanks the supports from NSF (CHE-1503865), the Welch foundation under Award No. C-1752, Packard fellowship, and Sloan fellowship. Y.Z. thanks a Schlumberger future faculty award.
    Publisher
    Wiley
    Journal
    Chemistry – An Asian Journal
    DOI
    10.1002/asia.201600169
    PubMed ID
    27101381
    Additional Links
    http://doi.wiley.com/10.1002/asia.201600169
    https://rss.onlinelibrary.wiley.com/doi/am-pdf/10.1002/asia.201600169
    ae974a485f413a2113503eed53cd6c53
    10.1002/asia.201600169
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC)

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