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    Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxides

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    Type
    Article
    Authors
    Paniagua, Sergio A.
    Giordano, Anthony J.
    Smith, O’Neil L.
    Barlow, Stephen cc
    Li, Hong cc
    Armstrong, Neal R.
    Pemberton, Jeanne E.
    Bredas, Jean-Luc cc
    Ginger, David
    Marder, Seth R. cc
    KAUST Department
    KAUST Solar Center (KSC)
    Laboratory for Computational and Theoretical Chemistry of Advanced Materials
    Material Science and Engineering Program
    Physical Science and Engineering (PSE) Division
    Date
    2016-05-26
    Online Publication Date
    2016-05-26
    Print Publication Date
    2016-06-22
    Permanent link to this record
    http://hdl.handle.net/10754/621569
    
    Metadata
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    Abstract
    Transparent conducting oxides (TCOs), such as indium tin oxide and zinc oxide, play an important role as electrode materials in organic-semiconductor devices. The properties of the inorganic-organic interface - the offset between the TCO Fermi level and the relevant transport level, the extent to which the organic semiconductor can wet the oxide surface, and the influence of the surface on semiconductor morphology - significantly affect device performance. This review surveys the literature on TCO modification with phosphonic acids (PAs), which has increasingly been used to engineer these interfacial properties. The first part outlines the relevance of TCO surface modification to organic electronics, surveys methods for the synthesis of PAs, discusses the modes by which they can bind to TCO surfaces, and compares PAs to alternative organic surface modifiers. The next section discusses methods of PA monolayer deposition, the kinetics of monolayer formation, and structural evidence regarding molecular orientation on TCOs. The next sections discuss TCO work-function modification using PAs, tuning of TCO surface energy using PAs, and initiation of polymerizations from TCO-tethered PAs. Finally, studies that examine the use of PA-modified TCOs in organic light-emitting diodes and organic photovoltaics are compared. © 2016 American Chemical Society.
    Citation
    Paniagua SA, Giordano AJ, Smith OL, Barlow S, Li H, et al. (2016) Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxides. Chem Rev 116: 7117–7158. Available: http://dx.doi.org/10.1021/acs.chemrev.6b00061.
    Sponsors
    The authors thank the National Science Foundation (through the Science and Technology Center Program, DMR-0120967, and a Graduate Research Fellowship, DGE-0644493), the U.S. Department of Energy (through the Center for Interface Science: Solar-Electric Materials (CIS:SEM), an Energy Frontier Research Center), Solvay SA, and the Department of Defense (through a National Defense Science and Engineering Graduate Fellowship) for supporting their work on phosphonic acids.
    Publisher
    American Chemical Society (ACS)
    Journal
    Chemical Reviews
    DOI
    10.1021/acs.chemrev.6b00061
    PubMed ID
    27227316
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.chemrev.6b00061
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Material Science and Engineering Program; KAUST Solar Center (KSC)

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