Selective Oxidation of Glycerol to Glyceric Acid in Base-Free Aqueous Solution at Room Temperature Catalyzed by Platinum Supported on Carbon Activated with Potassium Hydroxide
El Tall, Omar
Hedhili, Mohamed N.
KAUST DepartmentAnalytical Core Lab
Advanced Membranes and Porous Materials Research Center
Nano imaging lab; King Abdullah University of Science and Technology; Thuwal 23955-6900 Saudi Arabia
Water Desalination and Reuse Research Center (WDRC)
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AbstractPt supported on KOH-activated mesoporous carbon (K-AMC) was used to catalyze glycerol oxidation under base-free conditions at room temperature. To study the relationship between the carbon surface chemistry and the catalytic performance of the K-AMC-based Pt catalysts, different levels of surface oxygen functional groups (SOFGs) on the AMC supports were induced by thermal treatment at different temperatures under inert or H2 gas. A strong effect of the surface chemistry was observed on AMC-supported Pt catalysts for glycerol oxidation. The presence of carboxylic acid groups impedes the adsorption of glycerol, which leads to the reduction of catalytic activity, whereas the presence of high-desorption-temperature SOFGs, such as phenol, ether, and carbonyl/quinone groups, provide hydrophilicity to the carbon surface that improves the adsorption of glycerol molecules on Pt metal surface, which is beneficial for the catalytic activity. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
CitationTan H, Tall OE, Liu Z, Wei N, Yapici T, et al. (2016) Selective Oxidation of Glycerol to Glyceric Acid in Base-Free Aqueous Solution at Room Temperature Catalyzed by Platinum Supported on Carbon Activated with Potassium Hydroxide. ChemCatChem 8: 1699–1707. Available: http://dx.doi.org/10.1002/cctc.201600052.