• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    Nanoporous amide networks based on tetraphenyladamantane for selective CO2capture

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Type
    Article
    Authors
    Zulfiqar, Sonia
    Mantione, Daniele
    El Tall, Omar
    Sarwar, Muhammad Ilyas
    Ruipérez, Fernando
    Rothenberger, Alexander
    Mecerreyes, David cc
    KAUST Department
    Analytical Chemistry Core Lab
    Chemical Science Program
    Physical Science and Engineering (PSE) Division
    Solids
    Date
    2016
    Permanent link to this record
    http://hdl.handle.net/10754/621422
    
    Metadata
    Show full item record
    Abstract
    Reduction of anthropogenic CO2 emissions and CO2 separation from post-combustion flue gases are among the imperative issues in the spotlight at present. Hence, it is highly desirable to develop efficient adsorbents for mitigating climate change with possible energy savings. Here, we report the design of a facile one pot catalyst-free synthetic protocol for the generation of three different nitrogen rich nanoporous amide networks (NANs) based on tetraphenyladamantane. Besides the porous architecture, CO2 capturing potential and high thermal stability, these NANs possess notable CO2/N2 selectivity with reasonable retention while increasing the temperature from 273 K to 298 K. The quantum chemical calculations also suggest that CO2 interacts mainly in the region of polar amide groups (-CONH-) present in NANs and this interaction is much stronger than that with N2 thus leading to better selectivity and affirming them as promising contenders for efficient gas separation. © The Royal Society of Chemistry 2016.
    Citation
    Zulfiqar S, Mantione D, El Tall O, Sarwar MI, Ruipérez F, et al. (2016) Nanoporous amide networks based on tetraphenyladamantane for selective CO2capture. J Mater Chem A 4: 8190–8197. Available: http://dx.doi.org/10.1039/c6ta01457g.
    Sponsors
    Dr Sonia Zulfiqar is very thankful for the financial support provided by the Marie Curie IIF grant "NABPIL" (No. 629050) from the European Commission under the 7th Framework Programme (FP7-PEOPLE-2013-IIF) and also appreciate the cooperation of Dr Jose Ignacio Santos for Solid State NMR facility, Inigo Perez Miqueo for BET measurements and Dr Monica Moreno for administrative support from UPV/EHU, San Sebastian, Spain. The authors would like to thank for technical and human support provided by IZO-SGI SGIker of UPV/EHU and European funding (ERDF and ESF). Daniele Mantione is very grateful for financial support provided through EU project FP7-PEOPLE-212-ITN 316832-OLIMPIA.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    J. Mater. Chem. A
    DOI
    10.1039/c6ta01457g
    Additional Links
    http://pubs.rsc.org/en/content/articlehtml/2016/ta/c6ta01457g
    ae974a485f413a2113503eed53cd6c53
    10.1039/c6ta01457g
    Scopus Count
    Collections
    Articles; Analytical Chemistry Core Lab; Physical Science and Engineering (PSE) Division; Chemical Science Program

    entitlement

     
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.