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dc.contributor.authorAlezi, Dalal
dc.contributor.authorSpanopoulos, Ioannis
dc.contributor.authorTsangarakis, Constantinos
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorAdil, Karim
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorO'Keeffe, Michael
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorTrikalitis, Pantelis N.
dc.date.accessioned2016-10-20T11:52:19Z
dc.date.available2016-10-20T11:52:19Z
dc.date.issued2016-09-24
dc.identifier.citationAlezi D, Spanopoulos I, Tsangarakis C, Shkurenko A, Adil K, et al. (2016) Reticular Chemistry at Its Best: Directed Assembly of Hexagonal Building Units into the Awaited Metal-Organic Framework with the Intricate Polybenzene Topology, pbz-MOF. Journal of the American Chemical Society 138: 12767–12770. Available: http://dx.doi.org/10.1021/jacs.6b08176.
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.doi10.1021/jacs.6b08176
dc.identifier.urihttp://hdl.handle.net/10754/621097
dc.description.abstractThe ability to direct the assembly of hexagonal building units offers great prospective to construct the awaited and looked-for hypothetical polybenzene (pbz) or “cubic graphite” structure, described 70 years ago. Here, we demonstrate the successful use of reticular chemistry as an appropriate strategy for the design and deliberate construction of a zirconium-based metal–organic framework (MOF) with the intricate pbz underlying net topology. The judicious selection of the perquisite hexagonal building units, six connected organic and inorganic building blocks, allowed the formation of the pbz-MOF-1, the first example of a Zr(IV)-based MOF with pbz topology. Prominently, pbz-MOF-1 is highly porous, with associated pore size and pore volume of 13 Å and 0.99 cm3 g–1, respectively, and offers high gravimetric and volumetric methane storage capacities (0.23 g g–1 and 210.4 cm3 (STP) cm–3 at 80 bar). Notably, the pbz-MOF-1 pore system permits the attainment of one of the highest CH4 adsorbed phase density enhancements at high pressures (0.15 and 0.21 g cm–3 at 35 and 65 bar, respectively) as compared to benchmark microporous MOFs.
dc.description.sponsorshipThis research has been cofinanced by the European Union and Greek national funds through the Operational Program “Education and Lifelong Learning” of the National Strategic Reference Framework, Research Funding Program: ARISTEIA II - 4862. Financial support by King Abdullah University of Science and Technology is gratefully acknowledged.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/full/10.1021/jacs.6b08176
dc.rightsACS Editors' Choice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
dc.rights.urihttp://pubs.acs.org/page/policy/authorchoice_termsofuse.html
dc.titleReticular Chemistry at Its Best: Directed Assembly of Hexagonal Building Units into the Awaited Metal-Organic Framework with the Intricate Polybenzene Topology, pbz-MOF
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionDepartment of Chemistry, University of Crete, Voutes 71003 Heraklion, Greece
dc.contributor.institutionSchool of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, United States
kaust.personAlezi, Dalal
kaust.personShkurenko, Aleksander
kaust.personAdil, Karim
kaust.personBelmabkhout, Youssef
kaust.personEddaoudi, Mohamed
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc1m8m8s
refterms.dateFOA2018-06-14T04:38:48Z
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Alezi, D., Spanopoulos, I., Tsangarakis, C., Shkurenko, A., Adil, K., Belmabkhout, Y., … Trikalitis, P. N. (2016). CCDC 1497835: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1m8m8s. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1m8m8s">10.5517/ccdc.csd.cc1m8m8s</a> HANDLE: <a href="http://hdl.handle.net/10754/624593">10754/624593</a></li></ul>
dc.date.published-online2016-09-24
dc.date.published-print2016-10-05


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