Show simple item record

dc.contributor.authorNielsen, Christian B.
dc.contributor.authorGiovannitti, Alexander
dc.contributor.authorSbircea, Dan-Tiberiu
dc.contributor.authorBandiello, Enrico
dc.contributor.authorNiazi, Muhammad Rizwan
dc.contributor.authorHanifi, David A.
dc.contributor.authorSessolo, Michele
dc.contributor.authorAmassian, Aram
dc.contributor.authorMalliaras, George G.
dc.contributor.authorRivnay, Jonathan
dc.contributor.authorMcCulloch, Iain
dc.date.accessioned2016-07-28T13:21:09Z
dc.date.available2016-07-28T13:21:09Z
dc.date.issued2016-08-08
dc.identifier.citationMolecular Design of Semiconducting Polymers for High-Performance Organic Electrochemical Transistors 2016 Journal of the American Chemical Society
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.pmid27444189
dc.identifier.doi10.1021/jacs.6b05280
dc.identifier.urihttp://hdl.handle.net/10754/617692
dc.description.abstractThe organic electrochemical transistor (OECT), capable of transducing small ionic fluxes into electronic signals in an aqueous envi-ronment, is an ideal device to utilize in bioelectronic applications. Currently, most OECTs are fabricated with commercially availa-ble conducting poly(3,4-ethylenedioxythiophene) (PEDOT)-based suspensions and are therefore operated in depletion mode. Here, we present a series of semiconducting polymers designed to elucidate important structure-property guidelines required for accumulation mode OECT operation. We discuss key aspects relating to OECT performance such as ion and hole transport, elec-trochromic properties, operational voltage and stability. The demonstration of our molecular design strategy is the fabrication of accumulation mode OECTs that clearly outperform state-of-the-art PEDOT based devices, and show stability under aqueous oper-ation without the need for formulation additives and cross-linkers.
dc.description.sponsorshipThis work was carried out with financial support from EC FP7 Project SC2 (610115), EC FP7 Project ArtESun (604397), EC FP7 Project PolyMed (612538), and EPSRC Project EP/G037515/1. E.B. thanks the Spanish Ministry of Economy and Competitiveness for his predoctoral contract. M.S. acknowledges support from the first edition of the BBVA Foundation Grants for Researchers and Cultural Creators.
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/jacs.6b05280
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/jacs.6b05280.
dc.titleMolecular Design of Semiconducting Polymers for High-Performance Organic Electrochemical Transistors
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentOrganic Electronics and Photovoltaics Group
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry and Centre for Plastic Electronics, Imperial College London, London SW7 2AZ, United Kingdom
dc.contributor.institutionMaterials Research Institute and School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom.
dc.contributor.institutionDepartment of Bioelectronics, École Nationale Supérieure des Mines, CMP-EMSE, MOC Gardanne, 13541, France.
dc.contributor.institutionDepartment of Chemistry, Stanford University, Stanford, CA 94305, USA.
dc.contributor.institutionInstituto de Ciencia Molecular, Universidad de Valencia, 46980 Paterna, Spain.
dc.contributor.institutionPalo Alto Research Center, Palo Alto, CA 94304, USA.
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personNiazi, Muhammad Rizwan
kaust.personAmassian, Aram
kaust.personMcCulloch, Iain
refterms.dateFOA2017-07-22T00:00:00Z
dc.date.published-online2016-08-08
dc.date.published-print2016-08-17


Files in this item

Thumbnail
Name:
jacs2E6b05280.pdf
Size:
1.001Mb
Format:
PDF
Description:
Accepted Manuscript

This item appears in the following Collection(s)

Show simple item record