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dc.contributor.authorKatsiev, Khabiboulakh
dc.contributor.authorLozova, Nataliya
dc.contributor.authorWang, Lu
dc.contributor.authorKatla, Saikrishna
dc.contributor.authorLi, Ruipeng
dc.contributor.authorMei, Wai Ning
dc.contributor.authorSkrabalak, Sara
dc.contributor.authorChalla, Challa
dc.contributor.authorLosovyj, Yaroslav
dc.date.accessioned2016-07-19T09:59:29Z
dc.date.available2016-07-19T09:59:29Z
dc.date.issued2016
dc.identifier.citationElectronic Structure of Au25 Clusters: Between Discrete and Continuous 2016 Nanoscale
dc.identifier.issn2040-3364
dc.identifier.issn2040-3372
dc.identifier.doi10.1039/C6NR02374F
dc.identifier.urihttp://hdl.handle.net/10754/617238
dc.description.abstractHere, an approach based on synchrotron resonant photoemission is emplyed to explore the transition between quantization and hybridization of the electronic structure in atomically precise ligand-stabilized nanoparticles. While the presence of ligands maintains quantization in Au25 clusters, their removal renders increased hybridization of the electronic states at the vicinity of the Fermi level. These observations are supported by DFT studies.
dc.description.sponsorshipResearch at the Center for Atomic-Level Catalyst Design (Energy Frontier Research Center) was funded by the U.S. Department of Energy, Office of Basic Energy Sciences under Award #DESC0001058. L. W and W.-N. M. acknowledge the support of Department of Energy (award #DE-EE0003174), Nebraska Center for Materials and Nanoscience, and the UNL Holland Computing Center with the associated USCMS Tier-2 site at the UNL. K.K acknowledge support of KAUST. Access to XPS is provided by NSF Award DMR MRI-1126394. The authors acknowledge helpful discussions with P. Dowben and O. Bakr.
dc.language.isoen
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/NR/C6NR02374F
dc.rightsArchived with thanks to Nanoscale
dc.titleElectronic Structure of Au25 Clusters: Between Discrete and Continuous
dc.typeArticle
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalNanoscale
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, Indiana University, Bloomington, Indiana 47405, United States
dc.contributor.institutionCenter for Atomic-Level Catalyst Design, Cain Department of Chemical Engineering, Center for Advanced Microstructures and Devices (CAMD), Louisiana State University, Baton Rouge, Louisiana 70806, United State
dc.contributor.institutionDepartment of Physics, University of Nebraska at Omaha, Omaha, Nebraska 68182, United States
dc.contributor.institutionCornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, New York 14850, United States
dc.contributor.institutionDepartment of Chemistry, Texas A&M University (TAMU), Texas 77843, United States
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personKatsiev, Khabiboulakh
refterms.dateFOA2017-07-15T00:00:00Z


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