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dc.contributor.authorBucci, Alberto
dc.contributor.authorMenendez Rodriguez, Gabriel
dc.contributor.authorBellachioma, Gianfranco
dc.contributor.authorZuccaccia, Cristiano
dc.contributor.authorPoater, Albert
dc.contributor.authorCavallo, Luigi
dc.contributor.authorMacchioni, Alceo
dc.date.accessioned2016-06-23T09:23:55Z
dc.date.available2016-06-23T09:23:55Z
dc.date.issued2016-06-10
dc.identifier.citationAn Alternative Reaction Pathway for Iridium Catalyzed Water Oxidation Driven by CAN 2016 ACS Catalysis
dc.identifier.issn2155-5435
dc.identifier.issn2155-5435
dc.identifier.doi10.1021/acscatal.6b01325
dc.identifier.urihttp://hdl.handle.net/10754/614398
dc.description.abstractThe generation of solar fuels by means of a photosynthetic apparatus strongly relies on the development of an efficient water oxidation catalyst (WOC). Cerium ammonium nitrate (CAN) is the most commonly used sacrificial oxidant to explore the potentiality of WOCs. It is usually assumed that CAN has the unique role to oxidatively energize WOCs, making them capable to offer a low energy reaction pathway to transform H2O to O2. Herein we show that CAN might have a much more relevant and direct role in WO, mainly related to the capture and liberation of O–O containing molecular moieties.
dc.description.sponsorshipThis work was financially supported by SABIC, Regione Umbria (POR FSE Projects), and COST Action CM1205 (CARISMA). We thank Prof. Antoni Llobet for helpful discussions and Dr. Stefano Giovagnoli for his help in performing DLS measurements.
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acscatal.6b01325
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acscatal.6b01325.
dc.titleAn Alternative Reaction Pathway for Iridium Catalyzed Water Oxidation Driven by CAN
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalACS Catalysis
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Via Elce disotto, 8, I-06123 Perugia, Italy
dc.contributor.institutionInstitut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personCavallo, Luigi
refterms.dateFOA2017-06-10T00:00:00Z


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