Novel 6FDA-based polyimides derived from sterically hindered Tröger's base diamines: Synthesis and gas permeation properties
KAUST DepartmentAdvanced Membranes and Porous Materials Center (AMPMC)
Physical Sciences and Engineering (PSE) Division
Chemical and Biological Engineering Program
Imaging and Characterization Core Lab
Permanent link to this recordhttp://hdl.handle.net/10754/608226
MetadataShow full item record
AbstractTwo novel Tröger's base-based di-o-substituted diamine monomers were synthesized and used to prepare two intrinsically microporous 6FDA-based polyimides (PIM-PI-TB-1 and PIM-PI-TB-2) with high molecular weight, high thermal stability and excellent solubility in common organic solvents. Compared to previously reported methods for preparing TB-based diamines, which are based on reduction of dimerized nitro-substituted anilines or condensation of phenylenediamine derivatives with dianhydrides, the novel protocol can be used to prepare different functionalized TB-based diamine monomers from a wide variety of aniline derivatives. PIM-PI-TB-1 (made from 6FDA and dibromo-tetramethyl-substituted TB diamine) and PIM-PI-TB-2 (made from 6FDA and tetramethyl-substituted TB diamine) are intrinsically microporous polymers with high BET surface areas of 440 m2/g and 580 m2/g, respectively. Pure-gas permeability coefficients of He, H2, N2, O2, CH4, and CO2 were measured at 35 °C and 2 bar for fresh and 180 days aged films. Both TB-based polyimides exhibited high gas permeability with moderate selectivity. The gas permeability dropped significantly coupled with a moderate increase in selectivity after long-term physical aging of 180 days.
CitationNovel 6FDA-based polyimides derived from sterically hindered Tröger's base diamines: Synthesis and gas permeation properties 2016 Polymer
SponsorsThe research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST).