• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguideTheses and Dissertations LibguideSubmit an Item

    Statistics

    Display statistics

    Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    1860-5397-12-17.pdf
    Size:
    1.498Mb
    Format:
    PDF
    Description:
    Main article
    Download
    Thumbnail
    Name:
    1860-5397-12-17-S1.pdf
    Size:
    2.034Mb
    Format:
    PDF
    Description:
    Supplemental files
    Download
    Type
    Article
    Authors
    Wappel, Julia
    Fischer, Roland C
    Cavallo, Luigi cc
    Slugovc, Christian
    Poater, Albert cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016-01-28
    Permanent link to this record
    http://hdl.handle.net/10754/600717
    
    Metadata
    Show full item record
    Abstract
    A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested regarding their behavior in ROMP and especially for their use in the synthesis of poly(dicyclopentadiene) (pDCPD). Bearing either the common phosphine leaving ligand in the first and second Grubbs olefin metathesis catalysts, or the Ru–O bond cleavage for the next Hoveyda-type catalysts, this work is a step forward towards the control of polymer functionalization and living or switchable polymerizations.
    Citation
    Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands 2016, 12:154 Beilstein Journal of Organic Chemistry
    Sponsors
    A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN, and European Commission for a Career Integration Grant (CIG09-GA-2011-293900). L.C. thanks King Abdullah University of Science and Technology (CCF project) for support.
    Publisher
    Beilstein Institut
    Journal
    Beilstein Journal of Organic Chemistry
    DOI
    10.3762/bjoc.12.17
    PubMed ID
    26877818
    Additional Links
    http://www.beilstein-journals.org/bjoc/content/12/1/17
    Relations
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc1k9lyd HANDLE: 10754/663667
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc1k9lzf HANDLE: 10754/663668
    ae974a485f413a2113503eed53cd6c53
    10.3762/bjoc.12.17
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

    entitlement

    Related articles

    • Chelating ruthenium phenolate complexes: synthesis, general catalytic activity, and applications in olefin metathesis polymerization.
    • Authors: Kozłowska A, Dranka M, Zachara J, Pump E, Slugovc C, Skowerski K, Grela K
    • Issue date: 2014 Oct 20
    • Grubbs-Hoveyda type catalysts bearing a dicationic N-heterocyclic carbene for biphasic olefin metathesis reactions in ionic liquids.
    • Authors: Koy M, Altmann HJ, Autenrieth B, Frey W, Buchmeiser MR
    • Issue date: 2015
    • Hexacoordinate Ru-based olefin metathesis catalysts with pH-responsive N-heterocyclic carbene (NHC) and N-donor ligands for ROMP reactions in non-aqueous, aqueous and emulsion conditions.
    • Authors: Balof SL, Nix KO, Olliff MS, Roessler SE, Saha A, Müller KB, Behrens U, Valente EJ, Schanz HJ
    • Issue date: 2015
    • Hoveyda-Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable, industrially scalable, highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors.
    • Authors: Polyanskii KB, Alekseeva KA, Raspertov PV, Kumandin PA, Nikitina EV, Gurbanov AV, Zubkov FI
    • Issue date: 2019
    • Olefin metathesis catalysts bearing a pH-responsive NHC ligand: a feasible approach to catalyst separation from RCM products.
    • Authors: Balof SL, P'pool SJ, Berger NJ, Valente EJ, Shiller AM, Schanz HJ
    • Issue date: 2008 Nov 14
    DSpace software copyright © 2002-2022  DuraSpace
    Quick Guide | Contact Us | KAUST University Library
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.