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    Solution-Based Epitaxial Growth of Magnetically Responsive Cu@Ni Nanowires

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    Type
    Article
    Authors
    Zhang, Shengmao
    Zeng, Hua Chun
    Date
    2010-02-23
    Permanent link to this record
    http://hdl.handle.net/10754/600275
    
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    Abstract
    An experiment was conducted to show the solution-based epitaxial growth of magnetically responsive Cu@Ni nanowires. The Ni-sheathed Cu nanowires were synthesized with a one-pot approach. 30 mL of high concentration NaOH, Cu(NO3)2. 3H2O, Cu(NO3)2. 3H2O and 0.07-0.30 mL of Ni(NO3)2. 6H 2O aqueous solutions were added into a plastic reactor with a capacity of 50.0 mL. A varying amount of ethylenediamine (EDA) and hydrazine were also added sequentially, followed by thorough mixing of all reagents. The dimension, morphology, and chemical composition of the products were examined with scanning electron microscopy with energy dispersive X-ray spectroscopy. The XPS analysis on the as formed Cu nanowires confirms that there is indeed no nickel inclusion in the nanowires prior to the formation of nickel overcoat, which rules out the possibility of Cu-Ni alloy formation.
    Citation
    Zhang S, Zeng HC (2010) Solution-Based Epitaxial Growth of Magnetically Responsive Cu@Ni Nanowires. Chem Mater 22: 1282–1284. Available: http://dx.doi.org/10.1021/cm903105f.
    Sponsors
    The authors gratefully acknowledge the financial support of the Ministry of Education, Singapore, and King Abdullah University of Science and Technology, Saudi Arabia.
    Publisher
    American Chemical Society (ACS)
    Journal
    Chemistry of Materials
    DOI
    10.1021/cm903105f
    ae974a485f413a2113503eed53cd6c53
    10.1021/cm903105f
    Scopus Count
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