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dc.contributor.authorHuang, Ronglu
dc.contributor.authorHuang, Yangjie
dc.contributor.authorLin, Xiaoxi
dc.contributor.authorRong, Mingguang
dc.contributor.authorWeng, Zhiqiang
dc.date.accessioned2016-02-28T06:44:48Z
dc.date.available2016-02-28T06:44:48Z
dc.date.issued2015-03-17
dc.identifier.citationHuang R, Huang Y, Lin X, Rong M, Weng Z (2015) Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew Chem Int Ed 54: 5736–5739. Available: http://dx.doi.org/10.1002/anie.201501257.
dc.identifier.issn1433-7851
dc.identifier.pmid25783796
dc.identifier.doi10.1002/anie.201501257
dc.identifier.urihttp://hdl.handle.net/10754/600190
dc.description.abstract© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated. Efficiency drive: A series of copper(I) fluoroalkoxide complexes bearing N,N ligands have been prepared and structurally characterized. These well-defined complexes serve as efficient reagents for the fluoroalkoxylation of aryl and heteroaryl bromides to produce a wide range of trifluoroethyl, pentafluoropropyl, and tetrafluoropropyl (hetero)aryl ethers in good to excellent yields.
dc.description.sponsorshipFinancial support from the National Natural Science Foundation of China (NSFC) (grant number 21372044), the Research Fund for the Doctoral Program of Higher Education of China (grant number 20123514110003), and Fuzhou University (grant numbers 022318, 022494) is gratefully acknowledged. We thank Prof. Kuo-Wei Huang (KAUST) for insightful discussions.
dc.publisherWiley
dc.subjectC-O bonds
dc.subjectcopper
dc.subjectcross-coupling
dc.subjecttrifluoroethoxylation
dc.titleWell-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides
dc.typeArticle
dc.identifier.journalAngewandte Chemie International Edition
dc.contributor.institutionFuzhou University, Fuzhou, China
dc.date.published-online2015-03-17
dc.date.published-print2015-05-04


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