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    Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides

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    Type
    Article
    Authors
    Huang, Ronglu
    Huang, Yangjie
    Lin, Xiaoxi
    Rong, Mingguang
    Weng, Zhiqiang
    Date
    2015-03-17
    Online Publication Date
    2015-03-17
    Print Publication Date
    2015-05-04
    Permanent link to this record
    http://hdl.handle.net/10754/600190
    
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    Abstract
    © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated. Efficiency drive: A series of copper(I) fluoroalkoxide complexes bearing N,N ligands have been prepared and structurally characterized. These well-defined complexes serve as efficient reagents for the fluoroalkoxylation of aryl and heteroaryl bromides to produce a wide range of trifluoroethyl, pentafluoropropyl, and tetrafluoropropyl (hetero)aryl ethers in good to excellent yields.
    Citation
    Huang R, Huang Y, Lin X, Rong M, Weng Z (2015) Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew Chem Int Ed 54: 5736–5739. Available: http://dx.doi.org/10.1002/anie.201501257.
    Sponsors
    Financial support from the National Natural Science Foundation of China (NSFC) (grant number 21372044), the Research Fund for the Doctoral Program of Higher Education of China (grant number 20123514110003), and Fuzhou University (grant numbers 022318, 022494) is gratefully acknowledged. We thank Prof. Kuo-Wei Huang (KAUST) for insightful discussions.
    Publisher
    Wiley
    Journal
    Angewandte Chemie
    DOI
    10.1002/anie.201501257
    PubMed ID
    25783796
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.201501257
    Scopus Count
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