Tuning Structure and Properties of Graded Triblock Terpolymer-Based Mesoporous and Hybrid Films
AuthorsPhillip, William A.
Mika Dorin, Rachel
Hoek, Eric M. V.
KAUST Grant NumberKUS-C1-018-02
MetadataShow full item record
AbstractDespite considerable efforts toward fabricating ordered, water-permeable, mesoporous films from block copolymers, fine control over pore dimensions, structural characteristics, and mechanical behavior of graded structures remains a major challenge. To this end, we describe the fabrication and performance characteristics of graded mesoporous and hybrid films derived from the newly synthesized triblock terpolymer, poly(isoprene-b-styrene-b-4-vinylpyridine). A unique morphology, unachievable in diblock copolymer systems, with enhanced mechanical integrity is evidenced. The film structure comprises a thin selective layer containing vertically aligned and nearly monodisperse mesopores at a density of more than 1014 per m2 above a graded macroporous layer. Hybridization via homopolymer blending enables tuning of pore size within the range of 16 to 30 nm. Solvent flow and solute separation experiments demonstrate that the terpolymer films have permeabilities comparable to commercial membranes, are stimuli-responsive, and contain pores with a nearly monodisperse diameter. These results suggest that moving to multiblock polymers and their hybrids may open new paths to produce high-performance graded membranes for filtration, separations, nanofluidics, catalysis, and drug delivery. © 2011 American Chemical Society.
CitationPhillip WA, Mika Dorin R, Werner J, Hoek EMV, Wiesner U, et al. (2011) Tuning Structure and Properties of Graded Triblock Terpolymer-Based Mesoporous and Hybrid Films. Nano Lett 11: 2892–2900. Available: http://dx.doi.org/10.1021/nl2013554.
SponsorsThis publication is based on work supported by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST). R.M.D. acknowledges support from the NSF Graduate Research Fellowship Program (GRFP).
PublisherAmerican Chemical Society (ACS)
CollectionsPublications Acknowledging KAUST Support
- A simple route to highly oriented and ordered nanoporous block copolymer templates.
- Authors: Park S, Wang JY, Kim B, Xu J, Russell TP
- Issue date: 2008 Apr
- Morphology evolution in a diblock copolymer film.
- Authors: Song L, Lam YM
- Issue date: 2006 Dec
- Effect of the orientation of CdSe nanorods on the electron mobility of CdSe/P4VP nanodomains self-assembled within a poly(styrene-b-4-vinylpyridine) diblock copolymer thin film.
- Authors: Li CP, Yeh SW, Chang HC, Huang JY, Wei KH
- Issue date: 2006 Mar
- Nanoscale rings fabricated using self-assembled triblock terpolymer templates.
- Authors: Chuang VP, Ross CA, Bilalis P, Hadjichristidis N
- Issue date: 2008 Oct 28
- Constructional details of polystyrene-block-poly(4-vinylpyridine) ordered thin film morphology.
- Authors: Xue F, Li H, An L, Jiang S
- Issue date: 2013 Jun 1