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dc.contributor.authorLee, S. Y. Tina
dc.contributor.authorCokoja, Mirza
dc.contributor.authorDrees, Markus
dc.contributor.authorLi, Yang
dc.contributor.authorMink, János
dc.contributor.authorHerrmann, Wolfgang A.
dc.contributor.authorKühn, Fritz E.
dc.date.accessioned2016-02-28T06:35:16Z
dc.date.available2016-02-28T06:35:16Z
dc.date.issued2011-08-26
dc.identifier.citationLee SYT, Cokoja M, Drees M, Li Y, Mink J, et al. (2011) Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide. ChemSusChem 4: 1275–1279. Available: http://dx.doi.org/10.1002/cssc.201000445.
dc.identifier.issn1864-5631
dc.identifier.pmid21922679
dc.identifier.doi10.1002/cssc.201000445
dc.identifier.urihttp://hdl.handle.net/10754/600060
dc.description.abstractMu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.sponsorshipThis publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.
dc.publisherWiley
dc.subjectacrylic acid
dc.subjectcarbon dioxide fixation
dc.subjecthomogeneous catalysis
dc.subjectligand effects
dc.subjectnickel
dc.titleTransformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide
dc.typeArticle
dc.identifier.journalChemSusChem
dc.contributor.institutionTechnische Universitat Munchen, Munich, Germany
dc.contributor.institutionPannon Egyetem, Veszprem, Hungary
kaust.grant.numberKSA-C0069/UK-C0020
dc.date.published-online2011-08-26
dc.date.published-print2011-09-19


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