• Login
    View Item 
    •   Home
    • Office of Sponsored Research (OSR)
    • KAUST Funded Research
    • Publications Acknowledging KAUST Support
    • View Item
    •   Home
    • Office of Sponsored Research (OSR)
    • KAUST Funded Research
    • Publications Acknowledging KAUST Support
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Type
    Article
    Authors
    Lee, S. Y. Tina
    Cokoja, Mirza
    Drees, Markus
    Li, Yang
    Mink, János
    Herrmann, Wolfgang A.
    Kühn, Fritz E.
    KAUST Grant Number
    KSA-C0069/UK-C0020
    Date
    2011-08-26
    Online Publication Date
    2011-08-26
    Print Publication Date
    2011-09-19
    Permanent link to this record
    http://hdl.handle.net/10754/600060
    
    Metadata
    Show full item record
    Abstract
    Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Citation
    Lee SYT, Cokoja M, Drees M, Li Y, Mink J, et al. (2011) Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide. ChemSusChem 4: 1275–1279. Available: http://dx.doi.org/10.1002/cssc.201000445.
    Sponsors
    This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.
    Publisher
    Wiley
    Journal
    ChemSusChem
    DOI
    10.1002/cssc.201000445
    PubMed ID
    21922679
    ae974a485f413a2113503eed53cd6c53
    10.1002/cssc.201000445
    Scopus Count
    Collections
    Publications Acknowledging KAUST Support

    entitlement

    Related articles

    • Transformation of carbon dioxide with homogeneous transition-metal catalysts: a molecular solution to a global challenge?
    • Authors: Cokoja M, Bruckmeier C, Rieger B, Herrmann WA, Kühn FE
    • Issue date: 2011 Sep 5
    • A key step in the formation of acrylic acid from CO2 and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex.
    • Authors: Fischer R, Langer J, Malassa A, Walther D, Görls H, Vaughan G
    • Issue date: 2006 Jun 21
    • Carboxylation of methyl acrylate by carbon dioxide radical anions in gas-phase water clusters.
    • Authors: Akhgarnusch A, Höckendorf RF, Hao Q, Jäger KP, Siu CK, Beyer MK
    • Issue date: 2013 Aug 26
    • Method for the parallel synthesis of alpha-methylene-gamma-lactones from a fluorous acrylate.
    • Authors: Le Lamer AC, Gouault N, David M, Boustie J, Uriac P
    • Issue date: 2006 Sep-Oct
    • Evidence for spontaneous release of acrylates from a transition-metal complex upon coupling ethene or propene with a carboxylic moiety or CO(2).
    • Authors: Aresta M, Pastore C, Giannoccaro P, Kovács G, Dibenedetto A, Pápai I
    • Issue date: 2007
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.