The Architecture of Colloidal Quantum Dot Solar Cells: Materials to Devices
KAUST Grant NumberKUS-11-009-21
Online Publication Date2013-09-20
Print Publication Date2014-01-08
Permanent link to this recordhttp://hdl.handle.net/10754/599879
MetadataShow full item record
AbstractThe materials chemistry of Colloidal Quantum Dot (CQDs) suspended in solution and processed into films has provided a foundation onto which useful photovoltaic devices can be built. These active materials offer the benefits of solution processing paired with the flexibility of adjustable bandgaps, tailored to suit a particular need. In parallel with these advances, pursuing device geometries that better leverage the available electronic properties of CQD films has borne fruit in further advancing CQD solar cell performance. For active materials such as CQD films where 1/α, where alpha is the absorption coefficient, is of the same order as the free carrier extraction length, external quantum efficiency (EQE) measurements have proved useful in profiling the effectiveness of each nanometer of device thickness at extracting photogenerated carriers. Because CQD films have the added complications of being made of variable-sized constituent material building blocks as well as being deposited from solution, the nature of charge transport through the films can also be size-dependent and matrix dependent.
CitationKramer IJ, Sargent EH (2014) The Architecture of Colloidal Quantum Dot Solar Cells: Materials to Devices. Chem Rev 114: 863–882. Available: http://dx.doi.org/10.1021/cr400299t.
SponsorsThe authors would like to thank Oleksandr Voznyy for illuminating discussions on transport mechanisms in CQD films. This publication is based in part on work supported by Award KUS-11-009-21, made by King Abdullah University of Science and Technology (KAUST).
PublisherAmerican Chemical Society (ACS)
CollectionsPublications Acknowledging KAUST Support
- Preventing interfacial recombination in colloidal quantum dot solar cells by doping the metal oxide.
- Authors: Ehrler B, Musselman KP, Böhm ML, Morgenstern FS, Vaynzof Y, Walker BJ, Macmanus-Driscoll JL, Greenham NC
- Issue date: 2013 May 28
- Colloidal quantum dot photovoltaics: a path forward.
- Authors: Kramer IJ, Sargent EH
- Issue date: 2011 Nov 22
- Improving the performance of colloidal quantum-dot-sensitized solar cells.
- Authors: Giménez S, Mora-Seró I, Macor L, Guijarro N, Lana-Villarreal T, Gómez R, Diguna LJ, Shen Q, Toyoda T, Bisquert J
- Issue date: 2009 Jul 22
- The donor-supply electrode enhances performance in colloidal quantum dot solar cells.
- Authors: Maraghechi P, Labelle AJ, Kirmani AR, Lan X, Adachi MM, Thon SM, Hoogland S, Lee A, Ning Z, Fischer A, Amassian A, Sargent EH
- Issue date: 2013 Jul 23
- Selective contacts drive charge extraction in quantum dot solids via asymmetry in carrier transfer kinetics.
- Authors: Mora-Sero I, Bertoluzzi L, Gonzalez-Pedro V, Gimenez S, Fabregat-Santiago F, Kemp KW, Sargent EH, Bisquert J
- Issue date: 2013