Syntheses, characterizations, and catalytic activities of mesostructured aluminophosphates with tailorable acidity assembled with various preformed zeolite nanoclusters
Type
ArticleKAUST Grant Number
CRG-1-2012-LAI-009Date
2015-02-25Online Publication Date
2015-02-25Print Publication Date
2015-04Permanent link to this record
http://hdl.handle.net/10754/599829
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© 2015, Springer Science+Business Media New York. A series of ordered hexagonal mesoporous zeolites have been successfully synthesized by the assembly of various preformed aluminosilicates zeolite (MFI, FAU, BEA etc.) with surfactants (cetyltrimethylammonium chloride) under hydrothermal conditions. These unique samples were further characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption, infrared spectroscopy. Characterization results showed that these samples contain primary and secondary structural building units of various zeolites, which may be responsible for their distinguished acidic strength, suggesting that the acidic strength of these mesoporous silicoaluminophosphates could be tailored and controlled. Furthermore, the prepared samples were catalytically active in the cracking of cumene.Citation
Suo H, Zeng S, Wang R, Zhang Z, Qiu S (2015) Syntheses, characterizations, and catalytic activities of mesostructured aluminophosphates with tailorable acidity assembled with various preformed zeolite nanoclusters. J Porous Mater 22: 529–536. Available: http://dx.doi.org/10.1007/s10934-015-9923-y.Sponsors
This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (212611 30584, 91022030), "111" project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012).Publisher
Springer NatureJournal
Journal of Porous Materialsae974a485f413a2113503eed53cd6c53
10.1007/s10934-015-9923-y