KAUST Grant NumberKUS-C1-018-02
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AbstractOligomer-suspended SiO2-polyethylene glycol nanoparticles are studied as porous media electrolytes. At SiO2 volume fractions, , bracketing a critical value y ≈ 0.29, the suspensions jam and their mechanical modulus increase by more than seven orders. For >y, the mean pore diameter is close to the anion size, yet the ionic conductivity remains surprisingly high and can be understood, at all , using a simple effective medium model proposed by Maxwell. SiO 2-polyethylene glycol hybrid electrolytes are also reported to manifest attractive electrochemical stability windows (0.3-6.3 V) and to reach a steady-state interfacial impedance when in contact with metallic lithium. © 2010 The Royal Society of Chemistry.
CitationSchaefer JL, Moganty SS, Yanga DA, Archer LA (2011) Nanoporous hybrid electrolytes. J Mater Chem 21: 10094. Available: http://dx.doi.org/10.1039/c0jm04171h.
SponsorsThis work was supported by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), and by the National Science Foundation, Award No. DMR-1006323. JLN also acknowledges support from the Materials for a Sustainable Future IGERT program, NSF grant # DGE-0903653.
PublisherRoyal Society of Chemistry (RSC)
JournalJournal of Materials Chemistry