Layer-by-Layer-Assembled High-Performance Broadband Antireflection Coatings
KAUST Grant Number06/2008
MetadataShow full item record
AbstractNanoparticles are indispensable ingredients of solution-processed optical, dielectric, and catalytic thin films. Although solution-based methods are promising low-cost alternatives to vacuum methods, they can have significant limitations. Coating uniformity, thickness control, roughness control, mechanical durability, and incorporation of a diverse set of functional organic molecules into nanoparticle thin films are major challenges. We have used the electrostatic layer-by-layer assembly technique to make uniform, conformal multistack nanoparticle thin films for optical applications with precise thickness control over each stack. Two particularly sought-after optical applications are broadband antireflection and structural color. The effects of interstack and surface roughness on optical properties of these constructs (e.g., haze and spectral response) have been studied quantitatively using a combination of Fourier-transform methods and atomic force microscopy measurements. Deconvoluting root-mean-square roughness into its large-, intermediate-, and small-scale components enables enhanced optical simulations. A 4-stack broadband antireflection coating (<0.5% average reflectance in the visible range, and 0.2% haze) composed of alternating high-index (n ≈ 1.96) and low-index (n ≈ 1.28) stacks has been made on glass substrate. Films calcinated at 550 °C endure a one-hour-long cloth cleaning test under 100 kPa normal stress. © 2010 American Chemical Society.
CitationShimomura H, Gemici Z, Cohen RE, Rubner MF (2010) Layer-by-Layer-Assembled High-Performance Broadband Antireflection Coatings. ACS Applied Materials & Interfaces 2: 813–820. Available: http://dx.doi.org/10.1021/am900883f.
SponsorsWe thank JSR Corporation and the MIT MRSEC program of the National Science Foundation (Grant DMR 03-13282) for funding; the Center for Materials Science and Engineering (CMSE) and the Institute for Soldier Nanotechnologies (ISN) for access to shared equipment facilities: Dr. Larry Domash of Agiltron Inc for optical modeling using the Needle algorithm. Z.G. thanks KAUST for fellowship support (beginning 06/2008).
PublisherAmerican Chemical Society (ACS)
CollectionsPublications Acknowledging KAUST Support
- Spray-layer-by-layer assembly can more rapidly produce optical-quality multistack heterostructures.
- Authors: Nogueira GM, Banerjee D, Cohen RE, Rubner MF
- Issue date: 2011 Jun 21
- Hydrothermal treatment of nanoparticle thin films for enhanced mechanical durability.
- Authors: Gemici Z, Shimomura H, Cohen RE, Rubner MF
- Issue date: 2008 Mar 4
- Estimation of the average residual reflectance of broadband antireflection coatings.
- Authors: Tikhonravov AV, Trubetskov MK, Amotchkina TV, Dobrowolski JA
- Issue date: 2008 May 1
- Thermal cycling and the optical and electrical characterization of self-assembled multilayer nile blue A-gold thin films.
- Authors: Geist B, Spillman WB Jr, Claus RO
- Issue date: 2005 Oct 20
- Composite Layer-by-Layer (LBL) assembly with inorganic nanoparticles and nanowires.
- Authors: Srivastava S, Kotov NA
- Issue date: 2008 Dec