Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers
Type
ArticleAuthors
Widger, Peter C. B.Ahmed, Syud M.
Hirahata, Wataru
Thomas, Renee M.
Lobkovsky, Emil B.
Coates, Geoffrey W.
KAUST Grant Number
KUS-C1-018-02Date
2010Permanent link to this record
http://hdl.handle.net/10754/598678
Metadata
Show full item recordAbstract
A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers. © The Royal Society of Chemistry 2010.Citation
Widger PCB, Ahmed SM, Hirahata W, Thomas RM, Lobkovsky EB, et al. (2010) Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers. Chem Commun 46: 2935. Available: http://dx.doi.org/10.1039/b926888j.Sponsors
We acknowledge the NSF (CHE-0809778) and the King Abdullah University of Science and Technology (KAUST; Award No. KUS-C1-018-02) for support of this research. The authors are grateful for the help of T. Mourey at Kodak for polymer molecular weight determination.Publisher
Royal Society of Chemistry (RSC)Journal
Chemical CommunicationsISSN
1359-73451364-548X
DOI
10.1039/b926888jPubMed ID
20386828ae974a485f413a2113503eed53cd6c53
10.1039/b926888j
Scopus Count
Collections
Publications Acknowledging KAUST SupportRelated articles
- Enantioselective epoxide polymerization using a bimetallic cobalt catalyst.
- Authors: Thomas RM, Widger PC, Ahmed SM, Jeske RC, Hirahata W, Lobkovsky EB, Coates GW
- Issue date: 2010 Nov 24
- Enantioselective polymerization of epoxides: a highly active and selective catalyst for the preparation of stereoregular polyethers and enantiopure epoxides.
- Authors: Hirahata W, Thomas RM, Lobkovsky EB, Coates GW
- Issue date: 2008 Dec 31
- Isospecific, Chain Shuttling Polymerization of Propylene Oxide Using a Bimetallic Chromium Catalyst: A New Route to Semicrystalline Polyols.
- Authors: Childers MI, Vitek AK, Morris LS, Widger PCB, Ahmed SM, Zimmerman PM, Coates GW
- Issue date: 2017 Aug 16
- Asymmetric catalysis with water: efficient kinetic resolution of terminal epoxides by means of catalytic hydrolysis.
- Authors: Tokunaga M, Larrow JF, Kakiuchi F, Jacobsen EN
- Issue date: 1997 Aug 15
- A highly active, isospecific cobalt catalyst for propylene oxide polymerization.
- Authors: Peretti KL, Ajiro H, Cohen CT, Lobkovsky EB, Coates GW
- Issue date: 2005 Aug 24