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dc.contributor.authorCui, Li-Feng
dc.contributor.authorHu, Liangbing
dc.contributor.authorWu, Hui
dc.contributor.authorChoi, Jang Wook
dc.contributor.authorCui, Yi
dc.date.accessioned2016-02-25T13:33:26Z
dc.date.available2016-02-25T13:33:26Z
dc.date.issued2011
dc.identifier.citationCui L-F, Hu L, Wu H, Choi JW, Cui Y (2011) Inorganic Glue Enabling High Performance of Silicon Particles as Lithium Ion Battery Anode. J Electrochem Soc 158: A592. Available: http://dx.doi.org/10.1149/1.3560030.
dc.identifier.issn0013-4651
dc.identifier.doi10.1149/1.3560030
dc.identifier.urihttp://hdl.handle.net/10754/598629
dc.description.abstractSilicon, as an alloy-type anode material, has recently attracted lots of attention because of its highest known Li+ storage capacity (4200 mAh/g). But lithium insertion into and extraction from silicon are accompanied by a huge volume change, up to 300, which induces a strong strain on silicon and causes pulverization and rapid capacity fading due to the loss of the electrical contact between part of silicon and current collector. Silicon nanostructures such as nanowires and nanotubes can overcome the pulverization problem, however these nano-engineered silicon anodes usually involve very expensive processes and have difficulty being applied in commercial lithium ion batteries. In this study, we report a novel method using amorphous silicon as inorganic glue replacing conventional polymer binder. This inorganic glue method can solve the loss of contact issue in conventional silicon particle anode and enables successful cycling of various sizes of silicon particles, both nano-particles and micron particles. With a limited capacity of 800 mAh/g, relatively large silicon micron-particles can be stably cycled over 200 cycles. The very cheap production of these silicon particle anodes makes our method promising and competitive in lithium ion battery industry. © 2011 The Electrochemical Society.
dc.description.sponsorshipThe work is partially supported by the Global Climate and Energy Project at Stanford, Office of Naval Research and King Abdullah University of Science and Technology (KAUST) under the Award KUS-I1-001-12 (to Y.C.).
dc.publisherThe Electrochemical Society
dc.titleInorganic Glue Enabling High Performance of Silicon Particles as Lithium Ion Battery Anode
dc.typeArticle
dc.identifier.journalJournal of The Electrochemical Society
dc.contributor.institutionStanford University, Palo Alto, United States
kaust.grant.numberKUS-I1-001-12


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