Incorporating Multiple Energy Relay Dyes in Liquid Dye-Sensitized Solar Cells
Type
ArticleAuthors
Yum, Jun-HoHardin, Brian E.
Hoke, Eric T.
Baranoff, Etienne
Zakeeruddin, Shaik M.
Nazeeruddin, Mohammad K.
Torres, Tomas
McGehee, Michael D.
Grätzel, Michael
KAUST Grant Number
KUS-C1–015–21Date
2011-01-05Online Publication Date
2011-01-05Print Publication Date
2011-02-25Permanent link to this record
http://hdl.handle.net/10754/598608
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Panchromatic response is essential to increase the light-harvesting efficiency in solar conversion systems. Herein we show increased light harvesting from using multiple energy relay dyes inside dye-sensitized solar cells. Additional photoresponse from 400-590 nm matching the optical window of the zinc phthalocyanine sensitizer was observed due to Förster resonance energy transfer (FRET) from the two energy relay dyes to the sensitizing dye. The complementary absorption spectra of the energy relay dyes and high excitation transfer efficiencies result in a 35% increase in photovoltaic performance. © 2011 Wiley-VCH Verlag GmbH& Co. KGaA.Citation
Yum J-H, Hardin BE, Hoke ET, Baranoff E, Zakeeruddin SM, et al. (2011) Incorporating Multiple Energy Relay Dyes in Liquid Dye-Sensitized Solar Cells. ChemPhysChem 12: 657–661. Available: http://dx.doi.org/10.1002/cphc.201000854.Sponsors
The EPFL-affiliated authors thank the Swiss National Science Foundation for Financial Support. E. T. Hoke was funded by the Fannie and John Hertz Foundation. M. Grätzel and T. Torres were supported by EU Project ROBUST DSC, FP7-Energy-2007–1-RTD. This publication is partially based on work supported by the Center for Advanced Molecular Photovoltaics (Award No KUS-C1–015–21), made by King Abdullah University of Science and Technology (KAUST) gratefully acknowledged by M. Grätzel and M. McGehee. Financial support by the MEC, Spain (CTQ2008–00418/BQU, CONSOLIDER-INGENIO 2010 CDS 2007–00010, PLE2009–0070), and CAM (MADRISOLAR-2, S2009/PPQ/1533), is gratefully acknowledged by T. Torres.Publisher
WileyJournal
ChemPhysChemPubMed ID
21344598ae974a485f413a2113503eed53cd6c53
10.1002/cphc.201000854
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