Hybrid Zeolitic Imidazolate Frameworks: Controlling Framework Porosity and Functionality by Mixed-Linker Synthesis
AuthorsThompson, Joshua A.
Blad, Catherine R.
Brunelli, Nicholas A.
Lydon, Megan E.
Lively, Ryan P.
Jones, Christopher W.
KAUST Grant NumberKUS-Il-011-21
Online Publication Date2012-04-30
Print Publication Date2012-05-22
Permanent link to this recordhttp://hdl.handle.net/10754/598529
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AbstractZeolitic imidazolate frameworks (ZIFs) are a subclass of nanoporous metal-organic frameworks (MOFs) that exhibit zeolite-like structural topologies and have interesting molecular recognition properties, such as molecular sieving and gate-opening effects associated with their pore apertures. The synthesis and characterization of hybrid ZIFs with mixed linkers in the framework are described in this work, producing materials with properties distinctly different from the parent frameworks (ZIF-8, ZIF-90, and ZIF-7). NMR spectroscopy is used to assess the relative amounts of the different linkers included in the frameworks, whereas nitrogen physisorption shows the evolution of the effective pore size distribution in materials resulting from the framework hybridization. X-ray diffraction shows these hybrid materials to be crystalline. In the case of ZIF-8-90 hybrids, the cubic space group of the parent frameworks is continuously maintained, whereas in the case of the ZIF-7-8 hybrids there is a transition from a cubic to a rhombohedral space group. Nitrogen physisorption data reveal that the hybrid materials exhibit substantial changes in gate-opening phenomena, either occurring at continuously tunable partial pressures of nitrogen (ZIF-8-90 hybrids) or loss of gate-opening effects to yield more rigid frameworks (ZIF-7-8 hybrids). With this synthetic approach, significant alterations in MOF properties may be realized to suit a desired separation or catalytic process. © 2012 American Chemical Society.
CitationThompson JA, Blad CR, Brunelli NA, Lydon ME, Lively RP, et al. (2012) Hybrid Zeolitic Imidazolate Frameworks: Controlling Framework Porosity and Functionality by Mixed-Linker Synthesis. Chem Mater 24: 1930–1936. Available: http://dx.doi.org/10.1021/cm3006953.
SponsorsThis work was supported by King Abdullah University of Science and Technology under Award No. KUS-I1-011-21.
PublisherAmerican Chemical Society (ACS)
JournalChemistry of Materials