Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand
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AbstractAttempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.
CitationDespagnet-Ayoub E, Henling LM, Labinger JA, Bercaw JE (2013) Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand. Organometallics 32: 2934–2938. Available: http://dx.doi.org/10.1021/om4001567.
SponsorsThis work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094).
PublisherAmerican Chemical Society (ACS)