Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Type
Article
Authors
Despagnet-Ayoub, Emmanuelle
Henling, Lawrence M.
Labinger, Jay A.
Bercaw, John E.
Date
2013-05-09
Online Publication Date
2013-05-09
Print Publication Date
2013-05-24
Permanent link to this record
http://hdl.handle.net/10754/598435

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Abstract
Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.
Citation
Despagnet-Ayoub E, Henling LM, Labinger JA, Bercaw JE (2013) Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand. Organometallics 32: 2934–2938. Available: http://dx.doi.org/10.1021/om4001567.
Sponsors
This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094).
Publisher
American Chemical Society (ACS)
Journal
Organometallics
DOI
10.1021/om4001567
Collections
Publications Acknowledging KAUST Support