• Login
    View Item 
    •   Home
    • Office of Sponsored Research (OSR)
    • KAUST Funded Research
    • Publications Acknowledging KAUST Support
    • View Item
    •   Home
    • Office of Sponsored Research (OSR)
    • KAUST Funded Research
    • Publications Acknowledging KAUST Support
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    Fullerol ionic fluids

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Type
    Article
    Authors
    Fernandes, Nikhil
    Dallas, Panagiotis
    Rodriguez, Robert
    Bourlinos, Athanasios B.
    Georgakilas, Vasilios
    Giannelis, Emmanuel P.
    KAUST Grant Number
    KUS-C1-018-02
    Date
    2010
    Permanent link to this record
    http://hdl.handle.net/10754/598379
    
    Metadata
    Show full item record
    Abstract
    We report for the first time an ionic fluid based on hydroxylated fullerenes (fullerols). The ionic fluid was synthesized by neutralizing the fully protonated fullerol with an amine terminated polyethylene/polypropylene oxide oligomer (Jeffamine®). The ionic fluid was compared to a control synthesized by mixing the partially protonated form (sodium form) of the fullerols with the same oligomeric amine in the same ratio as in the ionic fluids (20 wt% fullerol). In the fullerol fluid the ionic bonding significantly perturbs the thermal transitions and melting/crystallization behavior of the amine. In contrast, both the normalized heat of fusion and crystallization of the amine in the control are similar to those of the neat amine consistent with a physical mixture of the fullerols/amine with minimal interactions. In addition to differences in thermal behavior, the fullerol ionic fluid exhibits a complex viscoelastic behavior intermediate between the neat Jeffamine® (liquid-like) and the control (solid-like). © 2010 The Royal Society of Chemistry.
    Citation
    Fernandes N, Dallas P, Rodriguez R, Bourlinos AB, Georgakilas V, et al. (2010) Fullerol ionic fluids. Nanoscale 2: 1653. Available: http://dx.doi.org/10.1039/c0nr00307g.
    Sponsors
    This publication is based on work supported in part by Award No. KUS-C1-018-02 made by King Abdullah University of Science and Technology (KAUST).
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Nanoscale
    DOI
    10.1039/c0nr00307g
    PubMed ID
    20820694
    ae974a485f413a2113503eed53cd6c53
    10.1039/c0nr00307g
    Scopus Count
    Collections
    Publications Acknowledging KAUST Support

    entitlement

    Related articles

    • Vibrational spectroscopy and ionic conductivity of polyethylene oxide-NaClO4-CuO nanocomposite.
    • Authors: Dey A, Das K, Karan S, De SK
    • Issue date: 2011 Dec
    • Fullerol in human lens and retinal pigment epithelial cells: time domain fluorescence spectroscopy and imaging.
    • Authors: Taroni P, D'Andrea C, Valentini G, Cubeddu R, Hu DN, Roberts JE
    • Issue date: 2011 Jun
    • Reduction of hydroxylated fullerene (fullerol) in water by zinc: reaction and hemiketal product characterization.
    • Authors: Wu J, Alemany LB, Li W, Petrie L, Welker C, Fortner JD
    • Issue date: 2014 Jul 1
    • Fullerol cluster formation in aqueous solutions: implications for environmental release.
    • Authors: Brant JA, Labille J, Robichaud CO, Wiesner M
    • Issue date: 2007 Oct 1
    • Activation Effect of Fullerene C60 on the Carbon Dioxide Absorption Performance of Amine-Rich Polypropylenimine Dendrimers.
    • Authors: Andreoli E, Barron AR
    • Issue date: 2015 Aug 24
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.