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    Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data

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    Type
    Article
    Authors
    Starikov, E.B.
    Nordén, B.
    Date
    2012-06
    Permanent link to this record
    http://hdl.handle.net/10754/598204
    
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    Abstract
    Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.
    Citation
    Starikov EB, Nordén B (2012) Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data. Chemical Physics Letters 538: 118–120. Available: http://dx.doi.org/10.1016/j.cplett.2012.04.028.
    Sponsors
    B.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST).
    Publisher
    Elsevier BV
    Journal
    Chemical Physics Letters
    DOI
    10.1016/j.cplett.2012.04.028
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.cplett.2012.04.028
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