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    Enantiospecific kinking of DNA by a partially intercalating metal complex

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    Type
    Article
    Authors
    Reymer, Anna
    Nordén, Bengt
    KAUST Grant Number
    KUK-11-008-23
    Date
    2012
    Permanent link to this record
    http://hdl.handle.net/10754/598163
    
    Metadata
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    Abstract
    Opposite enantiomers of [Ru(phenanthroline) 3] 2+ affect the persistence length of DNA differently, a long speculated effect of helix kinking. Our molecular dynamics simulations confirm a substantial change of duplex secondary structure produced by wedge-intercalation of one but not the other enantiomer. This effect is exploited by several classes of DNA operative proteins. © The Royal Society of Chemistry 2012.
    Citation
    Reymer A, Nordén B (2012) Enantiospecific kinking of DNA by a partially intercalating metal complex. Chem Commun 48: 4941. Available: http://dx.doi.org/10.1039/c2cc31176c.
    Sponsors
    This work was supported by King Abdullah University of Science and Technology, Grant [KUK-11-008-23] awarded to B.N.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/c2cc31176c
    PubMed ID
    22476247
    ae974a485f413a2113503eed53cd6c53
    10.1039/c2cc31176c
    Scopus Count
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